(Terpyridine)ruthenium trichloride
(Terpyridine)ruthenium trichloride is the coordination complex with the formula RuCl3(terpy), where terpy is terpyridine. It is a brown paramagnetic solid that is a precursor to other complexes of ruthenium, mainly by substitution of the chloride ligands. The complex has octahedral geometry.[1] It is prepared by heating ruthenium trichloride with a DMF solution of terpyridine.[2]
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| Identifiers | |
|---|---|
| Properties | |
| C15H11Cl3N3Ru | |
| Molar mass | 440.69 g·mol−1 |
| Appearance | brown solid |
| Density | 1.451 g/cm3 |
| insoluble | |
| Hazards | |
| GHS Signal word | Warning |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
References
- Ziegler, Marco; Monney, Véronique; Stoeckli-Evans, Helen; von Zelewsky, Alex; Sasaki, Isabelle; Dupic, Gilles; Daran, Jean-Claude; Balavoine, Gilbert G. A. (1999). "Complexes of New Chiral Terpyridyl Ligands. Synthesis and Characterization of Their Ruthenium(II) and Rhodium(III) Complexes". Journal of the Chemical Society, Dalton Transactions (5): 667–676. doi:10.1039/a900194h.
- Bessel, Carol A.; Leising, Randolph A.; Szczepura, Lisa F.; Perez, Willie J.; Vo Huyhn, My Hang; Takeuchi, Kenneth J. (1998). "Trichloro[2,2':6',2-terpyridine]ruthenium(III) and Phosphine Ligand Derivatives". Inorganic Syntheses. 32: 186-198. doi:10.1002/9780470132630.ch32.
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