2-Methyldodecane

2-Methyldodecane, an organic compound with a chemical formula C13H28, is an isomer of tridecane. It is produced by the reaction of 1-bromodecane and diisopropyl zinc.[3] Reaction of decylmagnesium bromide and 2-bromopropane produce 2-methyldodecane too.[4] Another method to produce 2-methyldodecane is react 1-dodecene and trimethylaluminium.[5]

2-Methyldodecane
Names
Other names
isotridecane
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 271-369-5
UNII
Properties
C13H28
Molar mass 184.367 g·mol−1
Density 0.754 g·cm−3(20 °C)[1]
Boiling point 103–104 °C (376–377 K)(10.5 Torr)[1]
227.7±3.0 °C(760 Torr)[2]
Hazards
GHS pictograms
GHS Signal word Danger
H304, H372, H373
P260, P264, P270, P301+310, P314, P331, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References

  1. Bashkirov, A. N.; Shaikhutdinov, E. M.; Gilyarovskaya, L. A. Oxidation of monomethyl-substituted paraffin hydrocarbons in the liquid phase in the presence of boric acid. Doklady Akademii Nauk SSSR, 1963. 148. 1309-1311. ISSN: 0002-3264.
  2. Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-06-11].
  3. Jun Terao, Hirohisa Todo, Hideyuki Watanabe, Aki Ikumi, Nobuaki Kambe (2004-11-19). "Nickel-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents with 1,3,8,10-Tetraenes as Additives". Angewandte Chemie International Edition. 43 (45): 6180–6182. doi:10.1002/anie.200460246. ISSN 1433-7851. PMID 15549748.CS1 maint: multiple names: authors list (link)
  4. Gérard Cahiez, Christophe Chaboche, Christophe Duplais, Arianna Giulliani, Alban Moyeux (2008-07-07). "Cobalt‐Catalyzed Cross‐Coupling Reaction between Functionalized Primary and Secondary Alkyl Halides and Aliphatic Grignard Reagents". Advanced Synthesis & Catalysis. 350 (10): 1484–1488. doi:10.1002/adsc.200800166.CS1 maint: multiple names: authors list (link)
  5. Stefan Mark, Nikola Gaidzik, Sven Doye, Markus Enders (2009). "Organochromium complexes as catalysts for the carboalumination of unactivated terminal olefins". Dalton Transactions (25): 4875–7. doi:10.1039/b902609f. ISSN 1477-9226. PMID 19662278. Retrieved 2020-06-19.CS1 maint: multiple names: authors list (link)
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.