9,10-Dithioanthracene
9,10-Dithioanthracene (DTA) is an organic molecule and a derivative of anthracene with two thiol groups. In 2004 DTA molecules were demonstrated to be able to "walk" in a straight line (reportedly a first ) on a metal surface by, in effect, mimicking the bipedal motion of a human being.[1][2] The sulfur-bearing functional groups on either side (referred to as "linkers") serve as the molecule's "feet". When the compound is heated on a flat copper surface, the linkers raise up, alternating from side to side, and propel the molecule forward.
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Preferred IUPAC name
Anthracene-9,10-dithiol | |
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C14H10S2 | |
Molar mass | 242.35 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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During testing at UC Riverside's Center for Nanoscale Science and Engineering, the molecule took about 10,000 unassisted nano-scale steps, moving in a straight line without requiring the assistance of nano-rails or nano-grooves for guidance. As described by one of the researchers, "Similar to a human walking, where one foot is kept on the ground while the other moves forward and propels the body, our molecule always has one linker on a flat surface, which prevents the molecule from stumbling to the side or veering off course."[3][4] Researchers believe the project could lead to the development of molecular computers in which DTA or other similar molecules would function as nano-abacuses.
References
- Molecular Machines and Motors Recent Advances and Perspectives Series: Topics in Current Chemistry, Vol. 354 Credi, Alberto, Silvi, Serena, Venturi, Margherita (Eds.) 2014
- Wilson, Elizabeth K. (September 27, 2005). "Molecules Take A Walk - Unidirectional motion gives researchers control important for molecular machines, self-assembly". C&EN. 83 (40). Retrieved November 5, 2014.
- Kwon, KY; Wong, KL; Pawin, G; Bartels, L; Stolbov, S; Rahman, TS (2005). "Unidirectional adsorbate motion on a high-symmetry surface: "walking" molecules can stay the course". Physical Review Letters. 95 (16): 166101. Bibcode:2005PhRvL..95p6101K. doi:10.1103/PhysRevLett.95.166101. PMID 16241817.
- "Molecule Walks Like a Human", UC Riverside News Release, September 26, 2005