Acetoguanamine

Acetoguanamine is an organic compound with the chemical formula (CNH2)2CCH3N3. It is related to melamine but with one amino group replaced by methyl. Acetoguanamine is used in the manufacturing of melamine resins. Unlike melamine ((CNH2)3N3), acetoguanamine is not a crosslinker. The "aceto" prefix is historical, the compound does not contain an acetyl group. A related compound is benzoguanamine.[2]

Acetoguanamine
Names
Systematic IUPAC name
6-Methyl-1,3,5-triazine-2,4-diamine[1]
Other names
Diamino-6-methyl-1,3,5-triazine
Identifiers
3D model (JSmol)
118348
ChEBI
ChemSpider
ECHA InfoCard 100.007.998
EC Number
  • 208-796-3
Properties
C4H7N5
Molar mass 125.135 g·mol−1
Appearance White, opaque crystals
Density 1.391 g cm−3
Melting point 274 to 276 °C (525 to 529 °F; 547 to 549 K)
Hazards
GHS pictograms
GHS Signal word Warning
H315, H319, H335
P261, P305+351+338
NFPA 704 (fire diamond)
Flammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilHealth code 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
1
0
Flash point 252 °C (486 °F; 525 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

The compound is prepared by condensation of cyanoguanidine with acetonitrile:

(H2N)2C=NCN + MeCN → (CNH2)2(CMe)N3

Safety

LD50 (oral, rats) is 2740 mg/kg.

References

  1. "Acetoguanamine - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology information.
  2. H. Deim; G. Matthias; R. A. Wagner (2012). "Amino Resins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a02_115.pub2.


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