Alkyl polyglycoside

Alkyl polyglycosides (APGs) are a class of non-ionic surfactants widely used in a variety of cosmetic, household, and industrial applications. Biodegradable and plant-derived from sugars, these surfactants are usually glucose derivatives, and fatty alcohols.[1] The raw materials are typically starch and fat, and the final products are typically complex mixtures of compounds with different sugars comprising the hydrophilic end and alkyl groups of variable length comprising the hydrophobic end.[2] When derived from glucose, they are known as alkyl polyglucosides.

General chemical structure of an alkyl polyglucoside, a common form of alkyl polyglycoside.

Uses

APG is used to enhance the formation of foams in detergents. It is also used in the personal care industry because it is biodegradable and safe for sensitive skin.[3]

Preparation

Alkyl glycosides are produced by combining a sugar such as glucose with a fatty alcohol in the presence of acid catalysts at elevated temperatures.[1][4]

References
  1. Karlheinz Hill; Wolfgang von Rybinski; Gerhard Stoll, eds. (2008). Alkyl Polyglycosides. Wiley-VCH. ISBN 978-3-527-61468-4.
  2. Iglauer, S.; Wu, Y.; Shuler, P.; Tang, Y. & Goddard, William A. III (2010). "Analysis of the Influence of Alkyl Polyglycoside Surfactant and Cosolvent Structure on Interfacial Tension in Aqueous Formulations versus n-Octane". Tenside Surfactants Detergents. 47 (2): 87–97.
  3. W von Rybinski; K Hill (1998). "Alkyl Polyglycosides—Properties and Applications of a new Class of Surfactants". Angewandte Chemie International Edition. 37 (10): 1328–1345. doi:10.1002/(SICI)1521-3773(19980605)37:10<1328::AID-ANIE1328>3.0.CO;2-9.
  4. Vishal Y. Joshi, Manohar R. Sawant, Novel stereo controlled glycosylation of 1,2,3,4,6-penta-o-acetyl-b-D-glucopyranoside using MgO–ZrO2 as an environmentally benign catalyst, Catalysis Communications 8 (2007) 1910–1916
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