Jan van Deemter
Jan Jozef van Deemter (31 March 1918 – 10 October 2004) was a Dutch physicist and engineer known for the Van Deemter equation in chromatography.[1][2][3]
Jan Jozef van Deemter | |
---|---|
Jan van Deemter | |
Born | 31 March 1918 |
Died | 10 October 2004 86) | (aged
Nationality | Dutch |
Alma mater | University of Groningen University of Amsterdam |
Known for | Van Deemter equation |
Scientific career | |
Institutions | Royal Dutch Shell |
Doctoral advisor | Bartel Leendert van der Waerden |
Van Deemter equation
The van Deemter equation relates the resolving power of a chromatographic column to the various flow and kinetic parameters which cause peak broadening through
Where HETP is the height equivalent theoretical plate, A is the eddy-diffusion parameter, B is the longitudinal diffusion coefficient of the eluting material in the longitudinal direction, C is the resistance to mass transfer coefficient of the analyte between mobile and stationary phase, and u is the linear velocity of the column flow.
References
- 75 Years of Chromatography: A Historical Dialogue. Elsevier. 26 August 2011. pp. 461–. ISBN 978-0-08-085817-3.
- van Deemter JJ, Zuiderweg FJ and Klinkenberg A (1956). "Longitudinal diffusion and resistance to mass transfer as causes of non ideality in chromatography". Chem. Eng. Sci. 5 (6): 271–289. doi:10.1016/0009-2509(56)80003-1.
- Ettre, Leslie S. (1979). "J.J. Van Deemter". 75 years of Chromatography a Historical Dialogue. Journal of Chromatography Library. 17. pp. 461–465. doi:10.1016/S0301-4770(08)60683-1. ISBN 9780444417541. ISSN 0301-4770.
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