Minyulite

Minyulite is a rare phosphate mineral with a chemical formula of KAl2(OH,F)(PO4)2·4(H2O).[3]

Minyulite
Colorless minyulite chrystals from Tom's Phosphate quarry, Kapunda, Mount Lofty Ranges, South Australia (Field of view 4 mm)
General
CategoryPhosphate mineral
Formula
(repeating unit)		KAl2(OH,F)(PO4)2·4(H2O)
Strunz classification8.DH.05
Crystal systemOrthorhombic
Crystal classPyramidal (mm2)
(same H-M symbol)
Space groupPba2
Unit cella = 9.34 Å, b = 9.74 Å,
c = 5.52 Å; Z = 2
Identification
Formula mass372.57 g/mol
ColorColorless to white, greenish yellow
Crystal habitRadiating fibrous to prismatic crystals
Cleavage{001} Perfect
FractureUneven - Flat surfaces (not cleavage) fractured in an uneven pattern.
TenacityBrittle
Mohs scale hardness3.5
LusterVitreous, silky in aggregates
StreakWhite
DiaphaneityTransparent
Specific gravity2.45
Optical propertiesBiaxial (+)
Refractive indexnα = 1.531 nβ = 1.534 nγ = 1.538
Birefringenceδ = 0.007
2V angleMeasured: 70° , calculated: 82°
References[1][2][3][4]

It occurs as groups of radiating fine fibrous crystals within rock cracks of phosphatic ironstone. Minyulite belongs to the orthorhombic crystal system. This indicates that it has three axes of unequal length yet all are perpendicular to each other. Its cell constants are a=9.35, b=9.74 c=5.52.[5]

As for its optical properties, Minyulite is an anisotropic mineral which means the velocity of light differs when traveling through it depending on the cut of its cross-section which gives it more than one refractive index.[6] The mineral is optically biaxial. Its birefringence value is 0.007.[7] It has three refractive indices which are nα=1.531 nβ=1.534 nγ=1.538.[8] Refractive indices are a ratio of the speed of light in a median with respect to the speed of light passing through the mineral.[6]

Occurrence
Minyulite (white) and sincosite (green), from Ross Hannibal Mine, Lead District, South Dakota, US (size: 7.1 x 5.4 x 2.7 cm)

It was first described in 1933 for an occurrence in Western Australia and named after the type locality, Minyulo Well in Western Australia.[2]

Minyulite is considered as a secondary phosphate since it is formed by the alteration of a primary phosphate. It occurs in association with dufrenite, apatite, fluellite, wavellite, variscite and leucophosphite.[3]

The mineral can be found in the underlying phosphatized rock zone of ornithogenic soil. Minyulite is not found in abundance, it can be found in the seashore of the maritime Arctic.[9]

References
  1. Mineralienatlas
  2. Minyulite at Mindat
  3. Handbook of Mineralogy
  4. Webmineral data
  5. Kampf, A.R. (1977) Minyulite: its atomic arrangement. American Mineralogist, 62, 256–262.
  6. Klein, C., and Dutrow, B.(2007) The 23rd Edition of the Manual of Mineral Science, 290 p. John Wiley and Sons, Inc. Hoboken, New Jersey, U.S.A.
  7. Spencer, L.J., F.A. Bannister, M.H. Hey, and H. Bennett (1943) Minyulite (hydrous K-Al fluophosphate) from South Australia. Mineralogical Magazine, 26, 309–314.
  8. Simpson, E.S., and Le Mesurier, C.R.(1933)Minyulite: a new phosphate mineral from Dandaragn. Journal of the Royal Society of Western Australia: 19-13.
  9. Tatur, A., and Keck, A. (1990) Phosphates in ornithogenic soils of the Maritime Antarctic.Proc. NIPR Symp. Polar Biol: 3, 133-150.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.