3-Nitrobenzyl alcohol
The compound 3-nitrobenzyl alcohol is an organic compound with the formula C7H7NO3.
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| Names | |
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| Preferred IUPAC name
(3-Nitrophenyl)methanol | |
| Other names
m-Nitrobenzyl alcohol Benzyl alcohol, m-nitro 3-Nitrobenzyl alcohol Benzenemethanol, 3-nitro- 3-Nitrobenzenemethanol | |
| Identifiers | |
3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.009.627  |
PubChem CID |
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| UNII | |
CompTox Dashboard (EPA) |
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| Properties | |
| C7H7NO3 | |
| Molar mass | 153.135 |
| Density | 1.29 g/mL |
| Melting point | 30 to 32 °C (86 to 90 °F; 303 to 305 K) |
| Boiling point | 175 to 180 °C (347 to 356 °F; 448 to 453 K) (3 mmHg) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
Desorption mass spectrometry matrix
In mass spectrometry this compound is often abbreviated as "3-NBA" or "m-NBA." It has been used as a liquid matrix for fast atom bombardment[1] and matrix-assisted laser desorption ionization.[2][3] In electrospray ionization 3-NBA is doped into low surface tension spray solvents to increase analyte charging.[4]
References
- Meili, J.; Seibl, J. (1984), "A new versatile matrix for fast atom bombardment analysis", Org. Mass Spectrom., 19 (11): 581, doi:10.1002/oms.1210191111
- Zhao, Shankai; Somayajula, Kasi V.; Sharkey, Andrew G.; Hercules, David M.; Hillenkamp, Franz.; Karas, Michael.; Ingendoh, Arndt. (1991), "Novel method for matrix-assisted laser mass spectrometry of proteins", Anal. Chem., 63 (5): 450, doi:10.1021/ac00005a012
- Chan, T. W. Dominic (1992), "Matrix-assisted laser desorption/ionization using a liquid matrix: Formation of high-mass cluster ions from proteins", Org. Mass Spectrom., 27 (1): 53–56, doi:10.1002/oms.1210270114
- Anthony T. Iavarone and Evan R. Williams (2003), "Mechanism of Charging and Supercharging Molecules in Electrospray Ionization", J. Am. Chem. Soc., 125 (8): 2319–2327, doi:10.1021/ja021202t, PMC 1343448, PMID 12590562
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