Cattiite

Cattiite is a phosphate mineral. The mineral was first found in a veins of dolomite carbonatites veins at the bottom of the Zhelezny (Iron) Mine in the Kovdor massif, Kola Peninsula, Russia. Cattiite was tentatively identified as Mg3(PO4)2 • 22H2O, which as a high hydrate magnesium orthophosphate. Later structural studies, revealed the existence of two polytypes named Mg3(PO4)2 • 22H2O-1A1 and Mg3(PO4)2 • 22H2O-1A2.[1] 

Cattiite
General
CategoryPhosphate Mineral
Formula
(repeating unit)		Mg3(PO4)2 • 22H2O
Strunz classification8.CE.50
Crystal systemTriclinic
Crystal classPinacoidal - (1)
Space groupP1
Unit cella = 6.932(2) Å,
b = 6.925(3) Å,
c = 16.154(5) Å,
α = 82.21(4)°,
β = 89.70(4)°,
γ = 119.51(3)°, Z = 1
Identification
Formula mass659.66 gm
ColorColorless
Crystal habitMassive, Granular
CleavagePerfect on (001)
FractureIrregular/Uneven
TenacityBrittle
Mohs scale hardness2
LusterVitreous, with gypsum-like pearly sheen on cleavage planes.
StreakWhite
DiaphaneityTransparent
Specific gravity1.65
Density1.65 g/cm3 (Measured)
1.64 g/cm3 (Calculated)
Optical propertiesBiaxial (−)
Refractive indexnα =1.459
nβ = 1.470
nγ = 1.470
Birefringenceδ = 0.011
PleochroismNon-pleochroic
References[1][2]

The polytype, Mg3(PO4)2 • 22H2O-1A2, had both the mineral and the name of the mineral approved (2000-032) by the Commission on New Minerals and Mineral Names or the (CNMMN) of the International Mineralogical Association or the (IMA). The name was approved by the CNMMN and the IMA was Cattiite. The mineral, Cattiite, was named that in the honor of the Michele Catti, Professor of Physical Chemistry at the University of Milano Bicocca in Italy, because of his work on the crystal chemistry of hydrated oxy-salts.[1]

Natural Occurrence and Localities

Cattiite bas been found in centimeter sized cavities that are within a 20–40 cm thick of the dolomite carbonatites that were enriched in late hydrothermal Mg-rich phosphates that was located at the Zhelezny Mine quarry. The vein of dolomite carbonatites that the Cattiite is found cross-cuts forsterite and magnetite ore that are located at the bottom of the mine's quarry. The mineral occurs as a mass that is up to 1.5 cm in size and usually contains a single crystal that fills the free space in the cavities and interstices of associated minerals. These associated minerals are dolomite, nastrophite, bakhchisaraitsevite, sjogrenite, magnetite, and carbonate-fluorapatite.[1]

Cattiite is also mined in Western Australia, Chile, France, Namibia, and United Kingdoms.[2]

Cattiite Properties

Crystallography

Cattiite is triclinic and has both very close cell parameters and crystal structures. The mineral has a space group of P1. The structures of the mineral are based on an isolated PO4 tetrahedra and Mg(H2O)6 octahedra that are joined by hydrogen bonds. The structures of the (001) sheets of the octahedra plus a sheet made of octahedra and tetrahedra form a polar (001) layer that is copied by a center of symmetry to form a layer with thickness that correlates with the c parameter. The X-ray single-crystal diffractometry of the mineral, Cattiite, has a cell that is a = 6.932(2) Å, b = 6.925(3) Å, c = 16.154(5) Å, α = 82.21(4)°, β = 89.70(4)°, γ = 119.51(3)°, V = 666.3(3) Å3, and Z = 1.[1]

Physical Properties

Cattiite usually occurs as a mass of single crystals that are sometimes shown to be the dominant form on the {001} axis. Along the {001} axis is where the percent cleavage located at, while the uneven fractures are in other directions. Luster of Cattiite is vitreous, with a gypsum-like pearly sheen that is on the perfect cleavage planes {001}. The mineral is colorless and transparent. Cattiite has a Mohs hardness of 2 and also a tenacity of being brittle. The specific gravity of the Cattiite is 1.65. The density of the mineral is 1.65 g/cm3 (Measured) and 1.64 g/cm3 (Calculated).[1]

It is non-pleochroic and bi-axial (-). The refractive index of the mineral is α = 1.459 (1), β = 1.470(1), and γ = 1.470(1). The optical orientation of Cattiite is X ^ [001] = 80°, Y ^ [100] = 10°, and Z is perpendicular to [001]. The minerals also has a weak dispersion, r < v.[1]

Chemical Properties

The high hydration that Cattiite has makes it unstable under heating. There were thermal studies done that showed that Mg3(PO4)2 • 22H2O as a synthetic at 70 °C, was partially dehydrated. This dehydration of the mineral began occurring ar 40-60 °C depending on the relative humidity in the air. It is easily soluble in diluted cold 10% hydrochloric acid (HCl). Cattiite also loses water under a vacuum when it was studied under an electron microprobe.[1]

See also

References
  1. Britvin,S.N.,Ferraris,G.,Ivaldi,G.,Bogdanova,A.N. & Chukanov,N.V. (2002): Cattiite,Mg 3(PO4)2 ·22H2O,anewmineralfromZheleznyMine(Kovdor Massif,KolaPeninsula,Russia).–N.Jb.Miner.Mh. 2002 (4):160–168;Stuttgart.
  2. Hudson Institute of Mineralogy, 2019, Cattiite: https://www.mindat.org/min-11456.html(accessed December 2019)
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