Inert gas

An inert gas is a gas that does not undergo chemical reactions under a set of given conditions. The noble gases often do not react with many substances[1] and were historically referred to as the inert gases. Inert gases are used generally to avoid unwanted chemical reactions degrading a sample. These undesirable chemical reactions are often oxidation and hydrolysis reactions with the oxygen and moisture in air. The term inert gas is context-dependent because several of the noble gases can be made to react under certain conditions.

Purified argon and nitrogen gases are most commonly used as inert gases due to their high natural abundance (78.3% N2, 1% Ar in air) and low relative cost.

Unlike noble gases, an inert gas is not necessarily elemental and is often a compound gas. Like the noble gases, the tendency for non-reactivity is due to the valence, the outermost electron shell, being complete in all the inert gases.[2] This is a tendency, not a rule, as noble gases and other "inert" gases can react to form compounds.

The group 18 elements include helium, neon, argon, krypton, xenon and radon. They are referred to as noble gases or inert gases. The general configuration of the valence shell is ns2np6. All of these elements occur in a free state in the atmosphere. They are colourless, tasteless and odorless gases. They exhibit low melting and boiling points. They have high positive electron gain enthalpy and high ionization enthalpy.

Production

The inert gases are obtained by fractional distillation of air, with the exception of helium which is separated from a few natural gas sources rich in this element,[3] through cryogenic distillation or membrane separation.[4] For specialized applications, purified inert gas shall be produced by specialized generators on-site. They are often used by chemical tankers and product carriers (smaller not a big as well as the tendency of inert gases vesselshtop specialized generators are also available for laboratories.

Applications

Because of the non-reactive properties of inert gases they are often useful to prevent undesirable chemical reactions from taking place. Food is packed in inert gas to remove oxygen gas. This prevents bacteria from growing.[5] It also prevents chemical oxidation by oxygen in normal air. An example is the rancidification (caused by oxidation) of edible oils. In food packaging, inert gases are used as a passive preservative, in contrast to active preservatives like sodium benzoate (an antimicrobial) or BHT (an antioxidant).

Historical documents may also be stored under an inert gas to avoid degradation. For example, the original documents of the U.S. Constitution are stored under humidified argon. Helium was previously used, but it was less suitable because it diffuses out of the case more quickly than argon.[6]

Inert gases are often used in the chemical industry. In a chemical manufacturing plant, reactions can be conducted under inert gas to minimize fire hazards or unwanted reactions. In such plants and in oil refineries, transfer lines and vessels can be purged with inert gas as a fire and explosion prevention measure. At the bench scale, chemists perform experiments on air-sensitive compounds using air-free techniques developed to handle them under inert gas. Helium, neon, argon, krypton, xenon, and radon are inert gases.

Inert gas systems on ships

Inert gas is produced on board crude oil carriers (above 8,000 tonnes)(from Jan 1, 2016) by using either a flue gas system or by burning kerosene in a dedicated inert gas generator. The inert gas system is used to prevent the atmosphere in cargo tanks or bunkers from coming into the explosive range.[7] Inert gases keep the oxygen content of the tank atmosphere below 5% (on crude carriers, less for product carriers and gas tankers), thus making any air/hydrocarbon gas mixture in the tank too rich (too high a fuel to oxygen ratio) to ignite. Inert gases are most important during discharging and during the ballast voyage when more hydrocarbon vapor is likely to be present in the tank atmosphere. Inert gas can also be used to purge the tank of the volatile atmosphere in preparation for gas freeing - replacing the atmosphere with breathable air - or vice versa.

The flue gas system uses the boiler exhaust as its source, so it is important that the fuel/air ratio in the boiler burners is properly regulated to ensure that high quality inert gases are produced. Too much air would result in an oxygen content exceeding 5%, and too much fuel oil would result in carryover of dangerous hydrocarbon gas. The flue gas is cleaned and cooled by the scrubber tower. Various safety devices prevent overpressure, the return of hydrocarbon gas to the engine room, or having a supply of IG with too high oxygen content.

Gas tankers and product carriers cannot rely on flue gas systems (because they require IG with O2 content of 1% or less) and so use inert gas generators instead. The inert gas generator consists of a combustion chamber and scrubber unit supplied by fans and a refrigeration unit which cools the gas. A drier in series with the system removes moisture from the gas before it is supplied to the deck. Cargo tanks on gas carriers are not inerted, but the whole space around them is. This arrangement allows the tanks to be kept cool using a small heel of cargo while the vessel is in ballast while retaining the explosion protection provided by the inert gas.

Inert gas systems on aircraft

Inert gas is produced on board commercial and military aircraft in order to passivate fuel tanks. On hot days, fuel vapor in fuel tanks may otherwise form a flammable or explosive mixture which if oxidized, could have catastrophic consequences. Conventionally, Air Separation Modules (ASMs) have been used to generate inert gas. ASMs contain selectively permeable membranes. They are fed compressed air which drives the separation of oxygen from the air. For fuel tank passivation, it is not necessary to remove all oxygen, but rather enough to stay below the lean flammability limit and the lean explosion limit.

Welding

In gas tungsten arc welding (GTAW), inert gases are used to shield the tungsten from contamination. It also shields the fluid metal (created from the arc) from the reactive gases in air which can cause porosity in the solidified weld puddle. Inert gases are also used in gas metal arc welding (GMAW) for welding non-ferrous metals.[8] Some gases which are not usually considered inert but which behave like inert gases in all the circumstances likely to be encountered in some use can often be used as a substitute for an inert gas. This is useful when an appropriate pseudo-inert gas can be found which is inexpensive and common. For example, carbon dioxide is sometimes used in gas mixtures for GMAW because it is not reactive to the weld pool created by arc welding. But it is reactive to the arc. The more carbon dioxide that is added to the inert gas, such as argon, will increase your penetration. The amount of carbon dioxide is often determined by what kind of transfer you will be using in GMAW. The most common is spray arc transfer, and the most commonly used gas mixture for spray arc transfer is 90% argon and 10% carbon dioxide. (Listed as many different names depending on the gas supplier).

Diving

In underwater diving an inert gas is a component of the breathing mixture which is not metabolically active, and serves to dilute the gas mixture. The inert gas may have effects on the diver, but these are thought to be mostly physical effects, such as tissue damage caused by bubbles in decompression sickness. The most common inert gases used in breathing gas for commercial diving are nitrogen and helium.

See also
  • Breathing gas – Gas used for human respiration
  • Industrial gas – Gaseous materials produced for use in industry
  • Inerting system for aircraft
  • Tank blanketing
  • Purging (gas), a fire and explosion prevention procedure to avoid the formation of an ignitable atmosphere, accomplished by flushing a closed system with an inert gas
  • Inerting (gas), a fire and explosion prevention procedure to make an ignitable atmosphere safe, accomplished by injecting an inert gas

References
  1. IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version:  (2006–) "inert gas". doi:10.1351/goldbook.I03027
  2. Singh, Jasvinder. The Sterling Dictionary of Physics. New Delhi, India: Sterling, 2007. 122.
  3. "Qatargas - Operations". www.qatargas.com. Retrieved 2018-08-31.
  4. "SEPURAN® Noble for helium recovery - SEPURAN® - Efficient gas separation". www.sepuran.com. Retrieved 2018-08-31.
  5. Maier, Clive & Teresa Calafut. Polypropylene: The Definitive User's Guide and Databook. Norwich, New York: Plastics Design Library, 1998. 105.
  6. "Charters of Freedom Re-encasement Project". National Archives. Retrieved 2012-02-11.
  7. International Maritime Organization. Tanker yes Familiarization London: Ashford Overload Services, 2000. 185.
  8. Davis, J.R., ed. Corrosion: Understanding the Basics. Materials Park, Ohio: ASM International, 2000. 188.
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