Kim Kimoon

Kim Kimoon (born 1954) is a South Korean chemist and professor in the Department of Chemistry at Pohang University of Science and Technology (POSTECH). He is the first and current director of the Center for Self-assembly and Complexity at the Institute for Basic Science. Kim has authored or coauthored 300 papers which have been cited more than 30,000 times[1] and he holds a number of patents.[2] His work has been published in Nature, Nature Chemistry, Angewandte Chemie, and JACS, among others. He has been a Clarivate Analytics Highly Cited Researcher in the field of chemistry in 2014, 2015, 2016.[3]

Kim Kimoon
Born1954 (age 66–67)
Seoul, South Korea
NationalitySouth Korean
Alma materSeoul National University (B.S., 1977)
Korea Advanced Institute of Science and Technology (M.S., 1979)
Stanford University (Ph.D., 1986)
Known forSupramolecular chemistry, self-assembly, cucurbituril, metal-organic framework
Awards Izatt-Christensen Award (2012)
Best Scientist and Engineer Award (2008)
Ho-Am Prize (2006)
Scientific career
FieldsChemistry
InstitutionsPohang University of Science and Technology, Institute for Basic Science, Yonsei University
ThesisElectrocatalytic four-electron reduction of dioxygen by metalloporphyrin adsorbed on graphite (1986)
Doctoral advisorsJames P. Collman, Mu Shik Jon
Korean name
Hangul
Hanja
Revised RomanizationGim Gi-mun
McCune–ReischauerKim Kimun
WebsiteCenter for Self-assembly and Complexity

His research has focused on developing novel functional materials and devices based on supramolecular chemistry.[4] In particular, his research group has worked on a various functional materials based on cucurbiturils (CB[n]s),[5][6][7][8][9] pumpkin-shaped macrocyclic molecules, and metal-organic porous materials for catalysis, separation, and gas storage.[10][11][12][13][14][15] His discovery and isolation of new members of the CB[n] family reported in 2000 had a major impact in expanding the field. Additionally, his paper published in Nature in 2000,[5] which reported the synthesis of homochiral nanoporous crystalline materials using self-assembly and an application for a chiral catalyst, is notable as it was placed among 35 top notable chemical related papers published in Nature from 1950 to 2000.[16] His research has been recognized by a number of awards, including the Izatt-Christensen Award in 2012.[17]

Education

Kim received his B.S. degree from Seoul National University in 1977, M.S. degree from Korea Advanced Institute of Science and Technology (KAIST) in 1979 under Prof. Mu Shik Jon, and Ph.D. degree from Stanford University in 1986 under Prof. James P. Collman. After graduating, he did two years of postdoctoral work at Northwestern University under Prof. James A. Ibers.

Career

Kim started his academic career at the Department of Chemistry at POSTECH in 1988, where he is now a Distinguished University Professor (POSTECH Fellow). In 1997, Kim was appointed director of the Center for Smart Supramolecules supported by the Creative Research Initiatives program under the Korean Ministry of Education, Science and Technology (MEST). He later founded the Division of Advanced Materials Science in POSTECH, launched in 2008 with support from the World Class University Project. On August 1, 2012, he was named founding director of the Center for Self-assembly and Complexity (CSC) under the Institute for Basic Science (IBS).[18] The center focuses on non-equilibrium self-assembly, molecular recognition in complex systems, and emergent materials.[19] In addition to his position in POSTECH, he also became an adjunct professor at the Yonsei Institute of Convergence Technology in Yonsei University in 2018.

Cucurbiturils

Cucurbiturils were first synthesized in 1905 by Robert Behrend, by condensing glycoluril with formaldehyde,[20] but their structure was not elucidated until 1981.[21] The field expanded as cucurbituril homologues CB5, CB7, and CB8 were discovered and isolated by Kim Kimoon in 2000, which laid the foundation for the development of cucurbituril-based chemistry and supramolecular chemistry.[22] Cucurbituril homologues display unique chemical properties as macrocyclic host molecules with exceptionally high binding affinities, and they have found use in host-guest chemistry and formation of supramolecular structures/assembly. This brought more attention to the field, allowing CB10 and CB14 to later be discovered.[23] The first CB-dedicated workshop was held in Maryland in 2007 with support from National Science Foundation[24] which paved the way for the International Conference on Cucurbiturils to be been held every two years from 2009 which was first organized by Kim and hosted at POSTECH.[25][26] His research on supermolecular chemistry, especially his work on cucurbituril, led him to receive the Izatt-Christensen Award.[17] In 2018, Kim co-authored the first textbook on cucurbiturils.[24][27]

Metal-organic framework

Kim has also focused his research on multifunctional modular porous materials, such as metal-organic frameworks and porous organic cages. Using an enantiopure organic building block and metal ion, his team was able to synthesize a homochiral metal–organic porous material, POST-1, and demonstrate that it works as a chiral catalyst.[5] his group contributed to the development of the modular porous materials field by demonstrating synthetic methodologies and applications. The team later designed and synthesized porphyrin boxes, a new class of porous organic cages consisting of porphyrins. Porphyrin boxes have been applied as a synthetic ion channel, electrochemical catalysis, and construction of hierarchical superstructures.[28]

Self-assembly via irreversible covalent bonds

Unlike conventional nanostructures built by reversible interactions/bonds, Kim discovered that the irreversible thiol-ene polymerization of rigid, disk-shaped building blocks resulted in robust hollow polymer nanocapsules with a narrow size distribution.[29] He was able to control the size, shape, property and functionality of the nanostructured materials, including spheres,[29][30] film,[31] toroids, and tubular structures.[32] They have applications in therapeutics,[33][34][35] catalysis,[36] separation,[37] and electronics. The research demonstrated an alternate route for construction of nanostructured materials with specific morphology via self-assembly.[38]

Awards

Memberships

See also

References
  1. "Director's Biography". Institute for Basic Science. Center for Self-assembly and Complexity. Retrieved 11 November 2018.
  2. "Patents by Inventor Ki-Moon Kim". Justia. Retrieved 11 February 2019.
  3. "IBS Places First Among Korean Institutions by Featuring 9 Scientists in List of Highly Cited Researchers". Institute for Basic Science. 4 December 2018. Retrieved 12 February 2019.
  4. "ICOMC 2018 - Kimoon Kim". 28th International Conference on Organometallic Chemistry. 2018. Retrieved 11 February 2019.
  5. Seo, Jung Soo; Whang, Dongmok; Lee, Hyoyoung; Jun, Sung Im; Oh, Jinho; Jeon, Young Jin; Kim, Kimoon (27 April 2000). "A homochiral metal-organic porous material for enantioselective separation and catalysis". Nature. 404 (6781): 982–986. Bibcode:2000Natur.404..982S. doi:10.1038/35010088. PMID 10801124. S2CID 1159701.
  6. Kim, Jaheon; Jung, In-Sun; Kim, Soo-Young; Lee, Eunsung; Kang, Jin-Koo; Sakamoto, Shigeru; Yamaguchi, Kentaro; Kim, Kimoon (2000). "New Cucurbituril Homologues: Syntheses, Isolation, Characterization, and X-ray Crystal Structures of Cucurbit[n]uril(n=5, 7, and 8)". Journal of the American Chemical Society. 122 (3): 540–541. doi:10.1021/ja993376p.
  7. J. W. Lee; S. Samal; N. Selvapalam; H.-J. Kim; K. Kim (2003). "Cucurbituril Homologues and Derivatives: New Opportunities in Supramolecular Chemistry". Acc. Chem. Res. 36 (8): 621–630. doi:10.1021/ar020254k. PMID 12924959. S2CID 16606191.
  8. D. N. Dybtsev; H. Chun; S. H. Yoon; D. Kim; K. Kim (2004). "Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties". J. Am. Chem. Soc. 126 (1): 32–33. doi:10.1021/ja038678c. PMID 14709045.
  9. D. N. Dybtsev; H. Chun; K. Kim (2004). "Rigid and Flexible: A Highly Porous Metal-Organic Framework with Unusual Guest-Dependent Dynamic Behavior". Angew. Chem. Int. Ed. 43 (38): 5033–5036. doi:10.1002/anie.200460712. PMID 15384114.
  10. D. N. Dybtsev; A. L. Nuzhdin; H. Chun; K. P. Bryliakov; E. P. Talsi; V. P. Fedin; K. Kim (2006). "A Homochiral Metal-Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity". Angew. Chem. Int. Ed. 45 (6): 916–920. doi:10.1002/anie.200503023. PMID 16385607.
  11. K. Kim; N. Selvapalam; Y. H. Ko; K. M. Park; D. Kim; J. Kim (2007). "Functionalized cucurbiturils and their applications". Chem. Soc. Rev. 36 (2): 267–279. doi:10.1039/b603088m. PMID 17264929.
  12. D. Kim; E. Kim; J. Kim; K. M. Park; K. Baek; M. Jung; Y. H. Ko; W. Sung; H. S. Kim; J. H. Suh; C. G. Park; O. S. Na; D.-k. Lee; K. E. Lee; S. S. Han; K. Kim (2007). "Direct Synthesis of Polymer Nanocapsules with a Noncovalently Tailorable Surface". Angew. Chem. Int. Ed. 46 (19): 3471–3474. doi:10.1002/anie.200604526. PMID 17221900. S2CID 7894440.
  13. M. Banerjee; S. Das; M. Yoon; H. J. Choi; M. H. Hyun; S. M. Park; G. Seo; K. Kim (2009). "Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials". J. Am. Chem. Soc. 131 (22): 7524–7525. doi:10.1021/ja901440g. PMID 19438178.
  14. S. Das; H. Kim; K. Kim (2009). "Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal-Organic Frameworks". J. Am. Chem. Soc. 131 (11): 3814–3815. doi:10.1021/ja808995d. PMID 19256486.
  15. D.-W. Lee; K. M. Park; M. Banerjee; S. H. Ha; T. Lee; K. Suh; S. Paul; H. Jung; J. Kim; N. Selvapalam; S. H. Ryu; K. Kim (2011). "Supramolecular fishing for plasma membrane proteins using an ultrastable synthetic host–guest binding pair". Nature Chemistry. 3 (2): 154–159. Bibcode:2011NatCh...3..154L. doi:10.1038/nchem.928. PMID 21258389.
  16. "Looking Back". Nature. Retrieved 10 October 2018.
  17. Lee, Suh-young (6 September 2011). "Prof. Kimoon Kim Wins the Izatt-Christensen Award". The Postech Times. POSTECH. Retrieved 11 February 2019.
  18. "Center for Self-assembly and Complexity - Chemistry - Research Centers". Institute for Basic Science. Retrieved 11 February 2019.
  19. "About CSC". Center for Self-assembly and Complexity. Institute for Basic Science. Retrieved 11 February 2019.
  20. Behrend, Robert (1905). "I. Ueber Condensationsproducte aus Glycoluril und Formaldehyd". Justus Liebig's Annalen der Chemie. 339: 1–37. doi:10.1002/jlac.19053390102.
  21. Freeman, W. A.; Mock, W. L.; Shih, N. Y. (1981). "Cucurbituril". Journal of the American Chemical Society. 103 (24): 7367–7368. doi:10.1021/ja00414a070.
  22. Kim, Jaheon; Jung, In-Sun; Kim, Soo-Young; Lee, Eunsung; Kang, Jin-Koo; Sakamoto, Shigeru; Yamaguchi, Kentaro; Kim, Kimoon (2000). "New Cucurbituril Homologues: Syntheses, Isolation, Characterization, and X-ray Crystal Structures of Cucurbit[n]uril(n=5, 7, and 8)". Journal of the American Chemical Society. 122 (3): 540–541. doi:10.1021/ja993376p.
  23. Cheng, Xiao-Jie; et al. (2013). "Twisted Cucurbit[14]uril". Angewandte Chemie International Edition. 52 (28): 7252–7255. doi:10.1002/ange.201210267. PMID 23716359.
  24. Kim, Kimoon (5 June 2018). Cucurbiturils: Chemistry, Supramolecular Chemistry and Applications. World Scientific. p. vii. ISBN 9781848164086.
  25. "ICCB 2009". ChemComm: 249–356. 21 January 2009. ISSN 1359-7345. Retrieved 11 February 2019.
  26. Masson, Eric; Ling, Xiaoxi; Joseph, Roymon; Kyeremeh-Mensah, Lawrence; Lu, Xiaoyong (9 December 2011). "Cucurbituril chemistry: a tale of supramolecular success". RSC Advances. 2012 (2): 1213–1247. doi:10.1039/C1RA00768H. Retrieved 11 February 2019. These numerical data support Kim’s wish expressed during the last evening of the 1st International Conference on Cucurbiturils (July 10–11, 2009)held at POSTECH in Pohang, Korea, that CB[n]s would be to the next decade what calixarenes have been to the previous one.
  27. 김, 하연 (28 August 2018). "포스텍 김기문 교수, 세계최초 쿠커비투릴 책 발간". Veritas-A (in Korean). Retrieved 11 February 2019.
  28. Mukhopadhyay, Rahul Dev; Kim, Younghoon; Koo, Jaehyoung; Kim, Kimoon (22 October 2018). "Porphyrin Boxes". Acc. Chem. Res. 51 (11): 2730–2738. doi:10.1021/acs.accounts.8b00302. PMID 30345738.
  29. Kim, Dongwoo; Kim, Eunju; Kim, Jeeyeon; Park, Kyeng Min; Baek, Kangkyun; Jung, Minseon; Ko, Young Ho; Sung, Wokyung; Kim, Hyung Seok; Suh, Ju Hyung; Park, Chan Gyung; Na, Oh Sung; Lee, Dong‐ki; Lee, Kyung Eun; Han, Sung Sik; Kim, Kimoon (27 April 2007). "Direct Synthesis of Polymer Nanocapsules with a Noncovalently Tailorable Surface". Angewandte Chemie. 46 (19): 3471–3474. doi:10.1002/anie.200604526. PMID 17221900. S2CID 7894440.
  30. Kim, Dongwoo; Kim, Eunju; Lee, Jiyeong; Hong, Soonsang; Sung, Wokyung; Lim, Namseok; Park, Chan Gyung; Kim, Kimoon (24 June 2010). "Direct Synthesis of Polymer Nanocapsules: Self-Assembly of Polymer Hollow Spheres through Irreversible Covalent Bond Formation". Journal of the American Chemical Society. 132 (28): 9908–9919. doi:10.1021/ja1039242. PMID 20572658. S2CID 207053581.
  31. Baek, Kangkyun; Yun, Gyeongwon; Kim, Youngkook; Kim, Dongwoo; Hota, Raghunandan; Hwang, Ilha; Xu, Dan; Ko, Young Ho; Gu, Gil Ho; Suh, Ju Hyung; Park, Chan Gyung; Sung, Bong June; Kim, Kimoon (2013). "Free-Standing, Single-Monomer-Thick Two-Dimensional Polymers through Covalent Self-Assembly in Solution". Journal of the American Chemical Society. 135 (17): 6523–6528. doi:10.1021/ja4002019. PMID 23574044.
  32. Lee, Jiyeong; Baek, Kangkyun; Kim, Myungjin; Yun, Gyeongwon; Ko, Young Ho; Lee, Nam-Suk; Hwang, Ilha; Kim, Jeehong; Natarajan, Ramalingam; Park, Chan Gyung; Sung, Wokyung; Kim, Kimoon (5 January 2014). "Hollow nanotubular toroidal polymer microrings". Nature Chemistry. 6 (2): 97–103. Bibcode:2014NatCh...6...97L. doi:10.1038/nchem.1833. PMID 24451584.
  33. Kim, Eunju; Kim, Dongwoo; Jung, Hyuntae; Lee, Jiyeong; Paul, Somak; Selvapalam, Narayanan; Yang, Yosep; Lim, Namseok; Park, Chan Gyung; Kim, Kimoon (14 June 2010). "Facile, Template‐Free Synthesis of Stimuli‐Responsive Polymer Nanocapsules for Targeted Drug Delivery". Angewandte Chemie. 49 (26): 4405–4408. doi:10.1002/anie.201000818. PMID 20468019.
  34. Hota, Raghunandan; Baek, Kangkyun; Yun, Gyeongwon; Kim, Youngkook; Jung, Hyuntae; Park, Kyeng Min; Yoon, Eunjin; Joo, Taiha; Kang, Juseok; Park, Chan Gyung; Bae, Su Mi; Ahn, Woong Shick; Kim, Kimoon (9 October 2012). "Self-assembled, covalently linked, hollow phthalocyanine nanospheres". Chem. Sci. 4 (1): 339–344. doi:10.1039/C2SC21254D.
  35. Roy, Indranil; Shetty, Dinesh; Hota, Raghunandan; Baek, Kangkyun; Kim, Jeesu; Kim, Chulhong; Kappert, Sandro; Kim, Kimoon (7 December 2015). "A Multifunctional Subphthalocyanine Nanosphere for Targeting, Labeling, and Killing of Antibiotic‐Resistant Bacteria". Angewandte Chemie International Edition. 54 (50): 15152–15155. doi:10.1002/anie.201507140. PMID 26493283.
  36. Yun, Gyeongwon; Hassan, Zahid; Lee, Jiyeong; Kim, Jeehong; Lee, Nam‐Suk; Kim, Nam Hoon; Baek, Kangkyun; Hwang, Ilha; Park, Chan Gyung; Kim, Kimoon (16 June 2014). "Highly Stable, Water‐Dispersible Metal‐Nanoparticle‐Decorated Polymer Nanocapsules and Their Catalytic Applications". Angewandte Chemie. 53 (25): 6414–6418. doi:10.1002/anie.201403438. PMID 24842492.
  37. Baek, Kangkyun; Xu, Dan; Murray, James; Kim, Sungwan; Kim, Kimoon (6 July 2016). "Permselective 2D-polymer-based membrane tuneable by host–guest chemistry". Chemical Communications. 52 (62): 9676–9678. doi:10.1039/C6CC03616C. PMID 27400648.
  38. Baek, Kangkyun; Hwang, Ilha; Roy, Indranil; Shetty, Dinesh; Kim, Kimoon (17 April 2015). "Self-Assembly of Nanostructured Materials through Irreversible Covalent Bond Formation". Accounts of Chemical Research. 48 (8): 2221–2229. doi:10.1021/acs.accounts.5b00067. PMID 25884270.
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