Nontronite

Nontronite is the iron(III) rich member of the smectite group of clay minerals. Nontronites typically have a chemical composition consisting of more than ~30% Fe2O3 and less than ~12% Al2O3 (ignited basis). Nontronite has very few economic deposits like montmorillonite[5][6] Like montmorillonite, nontronite can have variable amounts of adsorbed water associated with the interlayer surfaces and the exchange cations.

Nontronite
Nontronite from Slovakia
General
CategoryPhyllosilicates
Smectite group
Formula
(repeating unit)		(CaO0.5,Na)0.3Fe3+2(Si,Al)4O10(OH)2·nH2O
Strunz classification9.EC.40
Crystal systemMonoclinic
Space groupC2/m (no. 12)
Identification
ColorYellow, olive-green, green, orange, brown
Crystal habitEarthy masses
CleavagePerfect basal
Mohs scale hardness1.5 to 2
LusterEarthy to dull
StreakColorless
Specific gravity2.3
Optical propertiesBiaxial (-)
Refractive indexnα = 1.530 - 1.580 nβ = 1.555 - 1.612 nγ = 1.560 - 1.615
Birefringenceδ = 0.030 - 0.035
References[1][2][3][4]

A typical structural formula for nontronite is Ca.5(Si7Al.8Fe.2)(Fe3.5Al.4Mg.1)O20(OH)4.[7] The dioctahedral sheet of nontronite is composed mainly of trivalent iron (Fe3+) cations, although some substitution by trivalent aluminium (Al3+) and divalent magnesium (Mg2+) does occur. The tetrahedral sheet is composed mainly of silicon (Si4+), but can have substantial (about 1 in 8) substitution of either Fe3+ or Al3+, or combinations of these two cations. Thus, nontronite typically is characterised by having most (usually greater than 60%) of the layer charge located in the tetrahedral sheet. The layer charge is typically balanced by divalent calcium (Ca2+) or magnesium (Mg2+).

Nontronite forms from the weathering of biotite and basalts, precipitation of iron and silicon rich hydrothermal fluids and in deep sea hydrothermal vents.[8][9] Some evidence suggests that microorganisms may play an important role in their formation.[10] Microorganisms are also involved in reduction of structural iron in nontronite when soils undergo anoxia, and the reduced form of the clay appears to be highly reactive towards certain pollutants, perhaps contributing to the destruction of these compounds in the environment.[11][12]

The only known commercially viable and operational nontronite mine is located in Canterbury, New Zealand. The mine is operated by Palmer Resources and the finished products are used internationally in industrial applications (pulp & paper, surface coating) and in cosmetics marketed as New Zealand Glacial Clay.[13]

See also
  • Saponite – Trioctahedral (Mg2+, Fe2+) calcium smectite, phyllosilicate mineral

References
  1. Mineral Handbook http://rruff.geo.arizona.edu/doclib/hom/nontronite.pdf
  2. Webmineral data http://webmineral.com/data/Nontronite.shtml
  3. Mindat http://www.mindat.org/min-2924.html
  4. Dainyak, Lidia G.; Zviagina, Bella B.; Rusakov, Viacheslav S.; Drits, Victor A. (20 December 2006). "Interpretation of the nontronite-dehydroxylate Mossbauer spectrum using EFG calculations". European Journal of Mineralogy. 18 (6): 753–764. doi:10.1127/0935-1221/2006/0018-0753.
  5. Eggleton, 1977 Clay minerals,12:181-194
  6. Keeling et al., 2000 Clays and Clay Minerals, 48:537-548
  7. Mountainville nontronite, Gates et al., 2002 Clays and Clay Minerals, 50:223-239
  8. Bischoff, 1972, Clays and Clay Minerals, 20:217-223
  9. Eggleton 1975 American Mineralogist, 60:1063-1068)
  10. Kohler et al., 1994 Clays and Clay Minerals, 42:680-701
  11. Tor, J., C. Xu, J. M. Stucki, M. Wander, G. K. Sims. 2000. Trifluralin degradation under micro-biologically induced nitrate and Fe(III) reducing conditions. Env. Sci. Tech. 34:3148-3152.
  12. Xu, J., J. W. Stucki, J. Wu, J. Kostka, and G. K. Sims. 2001. Fate of atrazine and alachlor in redox-treated ferruginous smectite. Env. Tox. & Chem. 20: 2717-2724.
  13. Palmer Resources Limited, https://static1.squarespace.com/static/58c2277c2e69cf49f9b715cb/t/5901120586e6c0aad56c839e/1493242397999/New+Zealand+Glacial+Clay+Fact+Sheet
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