Manganese pentacarbonyl bromide

Manganese pentacarbonyl bromide is an organomanganese compound with the formula BrMn(CO)5. It is a bright orange solid that is a precursor to other manganese complexes. The compound is prepared by treatment of dimanganese decacarbonyl with bromine:[1]

Mn2(CO)10 + Br2 → 2 BrMn(CO)5
Manganese pentacarbonyl bromide
Names
Other names
bromopentacarbonylmanganese
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.035.005
EC Number
  • 238-522-8
Properties
C5BrMnO5
Molar mass 274.892 g·mol−1
Appearance orange solid
Hazards
GHS pictograms
GHS Signal word Warning
H302, H312, H332
P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

The complex undergoes substitution by a variety of donor ligands (L), e.g. to give derivatives of the type BrMn(CO)3L2.

The complex adopts an octahedral coordination geometry.[2]

References

  1. King, R. B. (1965). Organometallic Syntheses. Volume 1 Transition-Metal Compounds. New York: Academic Press. ISBN 0444426078.
  2. J. G. Hernandez, I. S. Butler, T. Friščić (214). "Multi-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions". Chemical Science. 5: 3576. doi:10.1039/C4SC01252F.CS1 maint: uses authors parameter (link)
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