Smoke! Smoke! Smoke! (That Cigarette)

The song is written in the talking blues style. Its narrator expresses disdain for the inventor of the cigarette, not so much for its health concerns (as he says he is an occasional smoker himself and it hasn't killed him yet) but because of its addictive effect on "nicotine slaves." He goes on to describe two situations, a tense poker game and a date with a beautiful woman, that are interrupted because the other person has a nicotine craving and needs a cigarette. Williams sarcastically quips that when the smoker eventually dies from the effects of their addiction, that they tell Saint Peter that they need a smoke before entering the golden gate.[4]

"Smoke! Smoke! Smoke! (That Cigarette)" was produced by Lee Gillette, and featured Johnny Weis, electric lead guitar; Eugene "Smokey" Rogers, acoustic rhythm guitar, harmony vocal; Earl "Joaquin" Murphey, steel guitar; Manny Klein, trumpet; Paul "Spike" Featherstone, harp; Andrew "Cactus" Soldi, Harry Sims, Rex Call, fiddles; Ossie Godson, piano; Deuce Spriggens, bass fiddle, harmony vocal; Milton "Muddy" Berry, drums; and Larry "Pedro" DePaul, accordion.

A cover version performed by Phil Harris stayed on the charts for 4 weeks, reaching number 8 on the "Best Sellers in Stores" chart. Williams made a stereophonic re-recording of the song for Capitol in 1960 on the album, Smoke! Smoke! Smoke!.[5] It has also been covered by Johnny Bond & His Red River Valley Boys in 1947, and by Sammy Davis Jr., who hit # 89 on the Country Charts in 1982,[6] Willie Nelson, Dennis Weaver, Michael Nesmith, Hank Thompson, Jimmy Dean, Commander Cody (Billboard #94 in 1973), Asleep at the Wheel, Doc Watson and others.[7] Thom Bresh, the son of the song's writer Merle Travis, hit #78 on the Country Charts with the song in 1978.[8] In France, Eddy Mitchell also recorded a french version of the song, on his album Rocking in Nashville (1974) : Fume cette cigarette.