Vanadium(III) iodide

Vanadium(III) iodide
Names
	IUPAC name Vanadium(III) iodide
	Other names Vanadium triiodide
Identifiers
CAS Number	15513-94-7 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.035.937
PubChem CID	3627252;
	InChI InChI=1S/3HI.V/h3*1H;/q;;;+3/p-3 Key: AAWFOGYSSVYINI-UHFFFAOYSA-K;
	SMILES [V](I)(I)I;
Properties
Chemical formula	VI3
Molar mass	431.6549 g/mol
Appearance	black solid
Density	5.14 g/cm3, solid
Solubility in water	soluble
Structure
Coordination geometry	octahedral
Related compounds
Other anions	Vanadium(III) bromide
Other cations	Titanium(III) iodide
Related compounds	VI2
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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	Infobox references

Vanadium(III) iodide is the inorganic compound with the formula VI₃. This paramagnetic solid is generated by the reaction of vanadium powder with iodine at around 500 °C.[1] The black hygroscopic crystals dissolve in water to give green solutions, characteristic of V(III) ions.

The purification of vanadium metal by the chemical transport reaction involving the reversible formation of vanadium(III) iodides in the presence of iodine and its subsequent decomposition to yield pure metal:

2 V + 3 I₂ ⇌ 2 VI₃

VI₃ crystallizes in the motif adopted by bismuth(III) iodide: the iodides are hexagonal-closest packed and the vanadium centers occupy one third of the octahedral holes.

When solid samples are heated, the gas contains VI₄, which is probably the volatile vanadium component in the vapor transport method. Thermal decomposition of the triiodide leaves a residue of vanadium(II) iodide:[2]

2 VI₃ → VI₂ + VI₄ ΔH = 36.6 kcal/mol; ΔS = 38.7 eu

References

Juza, D.; Giegling, D.; Schäfer, H. (1969). "Über die Vanadiniodide VJ₂ und VJ₃". Z. Anorg. Allg. Chem. 366 (3–4): 121–9. doi:10.1002/zaac.19693660303.
Berry, K. O.; Smardzewski, R. R.; McCarley, R. E. (1969). "Vaporization reactions of vanadium iodides and evidence for gaseous vanadium(IV) iodide". Inorg. Chem. 8 (9): 1994–7. doi:10.1021/ic50079a034.

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[ZaaC-1] Juza, D.; Giegling, D.; Schäfer, H. (1969). "Über die Vanadiniodide VJ₂ und VJ₃". Z. Anorg. Allg. Chem. 366 (3–4): 121–9. doi:10.1002/zaac.19693660303.

[2] Berry, K. O.; Smardzewski, R. R.; McCarley, R. E. (1969). "Vaporization reactions of vanadium iodides and evidence for gaseous vanadium(IV) iodide". Inorg. Chem. 8 (9): 1994–7. doi:10.1021/ic50079a034.