Dihydroquinine
Dihydroquinine, also known as hydroquinine,[1] is an organic compound and as a cinchona alkaloid closely related to quinine. The specific rotation is −148° in ethanol. A derivative of this molecule is used as chiral ligand in the AD-mix for Sharpless dihydroxylation.
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| Names | |
|---|---|
| IUPAC name
(R)-[(2S,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methanol | |
| Other names
(8α,9R)-10,11-Dihydro-6'-methoxycinchonan-9-ol | |
| Identifiers | |
3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.007.578  |
PubChem CID |
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| UNII | |
CompTox Dashboard (EPA) |
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| Properties | |
| C20H26N2O2 | |
| Molar mass | 326.440 g·mol−1 |
| Melting point | 173–175 °C |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
See also
References
- "Dihydroquinine chemical information". ChemIndustry.com.
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