Autunite

Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness of 2–​2 1⁄2.[3][4] Autunite crystallizes in the orthorhombic system and often occurs as tabular square crystals, commonly in small crusts or in fan-like masses. Due to the moderate uranium content of 48.27% it is radioactive and also used as uranium ore. Autunite fluoresces bright green to lime green under UV light. The mineral is also called calco-uranite, but this name is rarely used and effectively outdated.[5]

Autunite
Autunite from Daybreak Mine, Washington
General
CategoryPhosphate minerals
Formula
(repeating unit)		Ca(UO2)2(PO4)2·10–12H2O
Strunz classification8.EB.05
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPnma
Unit cella = 14.0135(6),
b = 20.7121(8),
c = 6.9959(3) [Å]; Z = 4
Identification
Formula mass986.26 g/mol
ColorLemon-yellow to sulfur-yellow, greenish yellow to pale green; may be dark green to greenish black
Crystal habitTabular crystals, foliated or scaly aggregates, and in crusts
TwinningRare on {110}
Cleavage{001} perfect, {100} and {010} poor
Fractureuneven
Mohs scale hardness2-2.5
LusterVitreous - pearly
StreakPale yellow
DiaphaneityTransparent to translucent
Specific gravity3.1-3.2
Density3.15
Optical propertiesBiaxial (-)
Refractive indexnα = 1.553 - 1.555 nβ = 1.575 nγ = 1.577 - 1.578
Birefringenceδ = 0.003
PleochroismX = colorless to pale yellow; Y = Z = yellow to dark yellow
2V angleMeasured: 10° to 53°
Ultraviolet fluorescenceStrong yellow-green fluorescence in UV; Radioactive
SolubilitySoluble in acids
Alters toDehydrates in air
Other characteristicsPseudotetragonal for synthetic material, Radioactive
References[1][2]

Autunite was discovered in 1852 near Autun, France, which is also autunite's namesake. It occurs as an oxidation product of uranium minerals in granite pegmatites and hydrothermal deposits. Associate minerals include metaautunite, torbernite, phosphuranylite, saleeite, uranophane and sabugalite.[2]

Etymology

Autunite was named after the town of Autun, France, where the mineral was initially found. The mineral was named by Henry J. Brooke and William H. Miller in 1854.[4] The archaic name "calco-uranite" pairs with the similarly composed mineral, torbernite, which was named "cupro-uranite". Both minerals are named due to their uranium content, with autunite's name referring to its calcium (calco), and torbernite's copper (cupro) quantity.[5]

Locations and mining

Mount Kit Carson, Washington
Autunite from Mount Kit Carson, Washington

Researchers found autunite inside the Daybreak Mine on Mount Kit Carson, Spokane, Washington (or sometimes referred to as "near Mount Spokane"), in "vugs, fractures, and shear zones in granitic rock". These areas showed signs of another phosphate, apatite, which may have helped lead to the formation of autunite, by providing a source of phosphate and lime. The formation may have occurred with the interaction of uranium leached from a separate deposit.[6]

90,000 lbs of U3O8 were produced from nine properties, although most of the ore came from the Daybreak Mine.[7]

Other locations

One of the other locations of autunite includes Autun, France, the type locality and namesake of the mineral. The mineral was formed there as an alteration of uraninite and other uranium bearing minerals.[8] Autunite is also found in Cornwall, Saxony, and North and South Dakota.[9][5]

Meta-autunite

If the mineral dries out, it can lose its water content and convert to meta-autunite-I, which can turn into meta-autunite-II after heating. These two subsequent minerals are very rare in nature. For scientific studies it is recommended to store the mineral in a sealed container to minimize the water loss. Museums are known to have covered the mineral with lacquer to avoid drying of the mineral.

  • Autunite under UV light
  • More crystals under UV light
  • Scaly crystals of autunite
  • Autunite from France
  • Close-up of an autunite crystal

References
  1. Mindat.org
  2. Handbook of Mineralogy
  3. Barthelmy, Dave. "Autunite Mineral Data". webmineral.com. Retrieved 2018-01-26.
  4. "Autunite: Autunite mineral information and data". www.mindat.org. Retrieved 2018-04-28.
  5. "Autunite" . Encyclopædia Britannica. 03 (11th ed.). 1911.
  6. G. W. Leo (1960). Autunite from Mt. Spokane, Washington. U.S. Geologic Survey, Menlo Park, California: The American Mineralogist. p. 1.
  7. USGS
  8. Publishing, D. K. (2012-06-18). Nature Guide: Rocks and Minerals. Penguin. ISBN 9781465403520.
  9. The Encyclopedia Americana: A Library of Universal Knowledge. Encyclopedia Americana Corporation. 1918. p. 669.
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