Kutnohorite

Kutnohorite is a rare calcium manganese carbonate mineral with magnesium and iron that is a member of the dolomite group. It forms a series with dolomite, and with ankerite. The end member formula is CaMn2+(CO3)2,[5] but Mg2+ and Fe2+ commonly substitute for Mn2+, with the Mn content varying from 38% to 84%,[1] so the formula Ca(Mn2+,Mg,Fe2+)(CO3)2 better represents the species. It was named by Professor Bukowsky in 1901 after the type locality of Kutná Hora, Bohemia, in the Czech Republic.[6] It was originally spelt “kutnahorite” but “kutnohorite” is the current IMA-approved spelling.

Kutnohorite
Kutnohorite, Wessels Mine, Kalahari manganese fields, Northern Cape Province, South Africa. Size 4.4 x 4.2 x 1.9 cm
General
CategoryCarbonate mineral
Formula
(repeating unit)		CaMn2+(CO3)2
Strunz classification5.AB.10
Dana classification14.2.1.3
Crystal systemTrigonal
Crystal classRhombohedral (3)
H-M symbol: (3)
Space groupR3
Identification
Formula mass215.0 g/mol (end member)
ColorWhite, pale pink or light brown
Crystal habitAggregates of bundled bladed crystals
CleavagePerfect on {1011}
FractureSubconchoidal
TenacityBrittle
Mohs scale hardness​3 1⁄2 to 4
LusterVitreous to dull
StreakWhite to pale pink
DiaphaneityTranslucent
Specific gravity3.12
Optical propertiesUniaxial (–)
Refractive indexNo = 1.727, Ne = 1.535[1][2]
No = 1.710 to 1.727, Ne = 1.519 to 1.535[3][4]
Diagnostic featuresPink colour, crystal habit and density.
SolubilitySoluble in acids
References[1][2][3][4]

Dolomite group

Unit cell

There are three formula units per unit cell (Z = 3) and the lengths of the sides are a close to 4.9 Å and c between 16 Å and 17 Å, although different sources give slightly different values, as follows:

a = 4.915 Å, c = 16.639 Å [1]
a = 4.8518(3) Å, c = 16.217(2) Å [3][4]
a = 4.85 Å, c = 16.34 Å [2]

Structure

The crystal class is trigonal 3, space group R3, the same as for the other members of the dolomite group. There are layers of (CO3)2− groups perpendicular to the long crystal axis c, and between these layers there are layers of the cations Ca2+ and Mn2+.[1] If there were perfect ordering amongst the cations they would separate into different layers, giving rise to the ordered sequence: Ca-(CO3)-Mn-(CO3)-Ca-(CO3)-Mn-(CO3)- along the c axis,[1] not all specimens, however, display such ordering.[7]

Optical properties

Kutnohorite may be white, pale pink or light brown. The pink shades are due to increased manganese and the brown colours are due to increased iron content. The mineral is translucent with a white to pale pink streak and vitreous to dull luster. It is uniaxial (-) with refractive indices No = 1.710 to 1.727 and Ne = 1.519 to 1.535, similar to dolomite. The ordinary refractive index, No, is high, comparable with spinel (1.719).

Physical properties

Kutnohorite occurs as aggregates of bundled blades of white through rose pink to light brown crystals. Also as simple rhombs with curved faces, polycrystalline spherules and in massive and granular habits. It has perfect rhombohedral cleavage, typical of carbonates. It is brittle with a subconchoidal fracture and it is quite soft, with hardness ​3 1⁄2 to 4, between calcite and fluorite. Specific gravity is 3.12, denser than both dolomite and calcite. It is soluble in acids, as are all carbonates.

Occurrence

Kutnohorite occurs typically in manganiferous sediments, associated with rhodochrosite, aragonite and calcite.[4] Notable occurrences include Tuscany, Italy and Kutná Hora, Czech Republic. It probably occurs at the Trepča Mines, Stari Trg, Kosovo, in the Balkans.[8] At the Eldorado Mine, Ouray County, Colorado, US, it occurs as tiny white crystals partially encrusting quartz and dolomite.[9] At the Ryujima Mine, Nagano Prefecture in Japan, magnesian kutnohorite occurs with quartz and rhodochrosite.[10] The type locality is Poličany, Kutná Hora, Central Bohemia Region, Bohemia, Czech Republic, and type material is conserved at Harvard University, Cambridge, Massachusetts, US.[4]

References
  1. Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley
  2. http://www.webmineral.com/data/Kutnohorite.shtml
  3. http://www.mindat.org/min-2299.html
  4. http://www.handbookofmineralogy.org
  5. http://rruff.info/ima
  6. Frondel, Clifford and Bauer, L H (1955), Kutnahorite, a manganese dolomite, CaMn(CO3)2. American Mineralogist 40: 748
  7. Peacor, D R, Essene, E J and Gaines, A M (1987) Petrologic and crystal-chemical implications of cation order-disorder in kutnahorite. American Mineralogist 72:319
  8. The Mineralogical Record (2007) 38-4:284
  9. Rocks & Minerals (2009) 84-5:423
  10. Akio Tsusue (1967) Magnesian Kutnahorite from Ryujima Mine, Japan. American Mineralogist 52:1751
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.