Tsumebite

Tsumebite is a rare phosphate mineral named in 1912 after the locality where it was first found, the Tsumeb mine in Namibia, well known to mineral collectors for the wide range of minerals found there. Tsumebite is a compound phosphate and sulfate of lead and copper, with hydroxyl, formula Pb2Cu(PO4)(SO4)(OH). There is a similar mineral called arsentsumebite, where the phosphate group PO4 is replaced by the arsenate group AsO4, giving the formula Pb2Cu(AsO4)(SO4)(OH). Both minerals are members of the brackebuschite group.

Tsumebite
Tsumebite from the Bluebell Claims, California, US.
General
CategoryPhosphate minerals
Formula
(repeating unit)		Pb2Cu(PO4)(SO4)(OH)
Strunz classification8.BG.05
Dana classification43.4.2.1
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/m
Identification
Formula mass685.99 g/mol
ColorEmerald-green, green in transmitted light
Crystal habitCrusts of intergrown crystals on matrix
TwinningAlmost always twinned. Twins may be multiple, with serrated re-entrants.
CleavageNone
FractureUneven
TenacityBrittle
Mohs scale hardness​3 1⁄2
LusterAdamantine to vitreous
StreakGreen
DiaphaneityTransparent
Specific gravity6.13
Optical propertiesBiaxial (+)
Refractive indexNx = 1.885 to 1.900, Ny = 1.920, Nz = 1.942 to 1.956
PleochroismFaint: X = Y = very pale blue to colorless; Z = robin’s-egg-blue[1][2]
SolubilityReadily soluble in HCl and slowly soluble in HNO3.[3]
References[1][3][4][5]

The brackebuschite group

The minerals in the brackebuschite group have the general formula A2B(H2O,OH)(TO4)2 and crystallise in the monoclinic system, space group P21/m. The group includes:[4]

  • brackebuschite Pb2Mn3+(VO4)2(OH)
  • arsenbrackebuschite Pb2(Fe3+,Zn)(AsO4)2(OH,H2O)
  • gamagarite Ba2Fe3+(VO4)2(OH)
  • goedkenite Sr2Al(PO4)2(OH)
  • bearthite Ca2Al(PO4)2OH
  • tsumebite Pb2Cu(PO4)(SO4)(OH)
  • arsentsumebite Pb2Cu(AsO4)(SO4)(OH)
  • vauquelinite Cu2+Pb2(CrO4)(PO4)(OH)
  • fornacite CuPb2(CrO4)(AsO4)(OH)
  • molybdofornacite CuPb2MoO4AsO4(OH)

Structure

The structure of the brackebuschite group minerals is composed of B-(O,OH)6 octahedra, two non-equivalent TO4 tetrahedra, TO4(1) and TO4(2), and two different irregular polyhedra of large cations. B and T represent different elements in different members of the group. Chains formed from the B octahedra link through the oxygens of TO4(2) tetrahedra, while the large cation polyhedra form double chains parallel to the b crystal axis through edge sharing with TO4(1) tetrahedra. The result is a tight three-dimensional structure.[4] In tsumebite copper ions occupy the B sites, and phosphorus and sulfur occupy the T sites. Lead is the large cation.

Unit cell

Tsumebite belongs to the monoclinic crystal class 2/m, meaning that it has one twofold axis of symmetry perpendicular to a mirror plane. The space group is P 21/m, meaning that the crystal lattice is a primitive lattice, with structural elements only at the vertices of the unit cell. These structural elements are made up of two formula units (Z = 2).
Unit cell parameters are a = 8.69 Å, b = 5.78 Å, c = 7.86 Å, β = 111.87°[3][4][5] or a = 8.70 Å, b = 5.80 Å, c = 7.85 Å, β = 111.5°.[1][2]

Optical properties

Tsumebite is an emerald-green color, transparent and green in transmitted light, with a green streak and an adamantine (diamond-like) to vitreous (glassy) luster. It is biaxial (+) with refractive indices Nx = 1.885 to 1.900, Ny = 1.920 and Nz = 1.942 to 1.956. It is faintly pleochroic with X = Y = very pale blue to colorless and Z = robin's-egg-blue.[1][2]

Physical properties

The mineral typically occurs as crusts of intergrown crystals on matrix. Cleavage is absent, but twinning is almost universal, and twins may be multiple, with serrated re-entrants.[1] It is brittle, with an uneven fracture, hardness ​3 1⁄2 and specific gravity 6.13. It is readily soluble in hydrochloric acid HCl and slowly soluble in nitric acid HNO3.[3] It is not radioactive.[5]

Environment

Tsumebite is a rare secondary mineral in the oxidised zone of some arsenic-bearing lead-copper deposits, with other lead-bearing phosphates and sulfates.[1] Associated minerals include azurite, smithsonite, malachite, cerussite, mimetite, wulfenite and olivenite.[1] The type locality is the Tsumeb mine, Tsumeb, Otjikoto Region, Namibia.[3] The Handbook of Mineralogy[1] states that the type material was destroyed by bombing, but does not indicate when or where.

Tsumebite occurs at Morenci, Arizona, predominantly as twinned crystals associated with wulfenite, olivenite and the hyalite variety of opal.[2] At Broken Hill, New South Wales, Australia, tsumebite has been found as lustrous pale blue to bluish green crystals. It usually occurs with yellow crusts of corkite-hinsdalite, colorless to white pyromorphite needles and sprays of pale greyish green zincian libethenite. Less commonly found with scholzite and torbernite.[6]

References
  1. Handbook of Mineralogy
  2. American Mineralogist (1966) 51: 258–259 and 267
  3. Mindat.org
  4. Gaines et al (1997) Dana’s New Mineralogy Eighth Edition, Wiley
  5. Webmineral data
  6. Australian Journal of Mineralogy (1997) 3-1:53
  • LaForge (1938) American Mineralogist: 23: 772
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