Malachite

Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur.[4]

For other uses, see Malachite (disambiguation).
Malachite
General
CategoryCarbonate mineral
Formula
(repeating unit)		Cu2CO3(OH)2
Strunz classification5.BA.10
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/a
Identification
Formula mass221.1 g/mol
ColorBright green, dark green, blackish green, with crystals deeper shades of green, even very dark to nearly black commonly banded in masses; green to yellowish green in transmitted light
Crystal habitMassive, botryoidal, stalactitic, crystals are acicular to tabular prismatic
TwinningCommon as contact or penetration twins on {100} and {201}. Polysynthetic twinning also present.
CleavagePerfect on {201} fair on {010}
FractureSubconchoidal to uneven
Mohs scale hardness3.5–4
LusterAdamantine to vitreous; silky if fibrous; dull to earthy if massive
Streaklight green
DiaphaneityTranslucent to opaque
Specific gravity3.6–4
Optical propertiesBiaxial (–)
Refractive indexnα = 1.655 nβ = 1.875 nγ = 1.909
Birefringenceδ = 0.254
References[1][2][3][4]

Etymology and history
The entrance to the Neolithic era malachite mine complex on the Great Orme

The stone's name derives (via Latin: molochītis, Middle French: melochite, and Middle English melochites) from Greek Μολοχίτης λίθος molochites lithos, "mallow-green stone", from μολόχη molochē, variant of μαλάχη malāchē, "mallow".[5] The mineral was given this name due to its resemblance to the leaves of the mallow plant.[6]

Malachite was extensively mined at the Great Orme Mines in Britain 3,800 years ago, using stone and bone tools. Archaeological evidence indicates that mining activity ended c. 600 BCE, with up to 1,760 tonnes of copper being produced from the mined Malachite.[7][8]

Archaeological evidence indicates that the mineral has been mined and smelted to obtain copper at Timna Valley in Israel for more than 3,000 years.[9] Since then, malachite has been used as both an ornamental stone and as a gemstone.

Occurrence

Malachite often results from the weathering of copper ores, and is often found with azurite (Cu3(CO3)2(OH)2), goethite, and calcite. Except for its vibrant green color, the properties of malachite are similar to those of azurite and aggregates of the two minerals occur frequently. Malachite is more common than azurite and is typically associated with copper deposits around limestones, the source of the carbonate.

Large quantities of malachite have been mined in the Urals, Russia. Ural malachite is not being mined at present,[10] but G.N Vertushkova reports the possible discovery of new deposits of malachite in the Urals.[11] It is found worldwide including in the Democratic Republic of the Congo; Gabon; Zambia; Tsumeb, Namibia; Mexico; Broken Hill, New South Wales; Lyon, France; Timna Valley, Israel; and the Southwestern United States, most notably in Arizona.[12]

Structure

Malachite crystallizes in the monoclinic system. The structure consists of chains of alternating Cu2+ ions and OH− ions, with a net positive charge, woven between isolated triangular CO32− ions. Thus each copper ion is conjugated to two hydroxyl ions and two carbonate ions; each hydroxyl ion is conjugated with two copper ions; and each carbonate ion is conjugated with six copper ions.[13][14]

  • View along c axis of the crystal structure of malachite
  • View along a axis of malachite crystal structure
  • View along b axis of malachite crystal structure

Use
The funerary mask of the Red Queen of Palenque is made from a mosaic of malachite.[15]

Malachite was used as a mineral pigment in green paints from antiquity until c. 1800.[16] The pigment is moderately lightfast, sensitive to acids, and varying in color. This natural form of green pigment has been replaced by its synthetic form, verditer, among other synthetic greens.

Malachite is also used for decorative purposes, such as in the Malachite Room in the Hermitage Museum, which features a huge malachite vase, and the Malachite Room in Castillo de Chapultepec in Mexico City. "The Tazza", a large malachite vase, one of the largest pieces of malachite in North America and a gift from Tsar Nicholas II, stands as the focal point in the centre of the room of Linda Hall Library.

Symbolism and superstitions

A 17th-century Spanish superstition held that having a child wear a lozenge of malachite would help them sleep, and keep evil spirits at bay.[17] Marbodus recommended malachite as a talisman for young people because of its protective qualities and its ability to help with sleep.[18] It has also historically been worn for protection from lightning and contagious diseases and for health, success, and constancy in the affections.[19] During the Middle Ages it was customary to wear it engraved with a figure or symbol of the Sun to maintain health and to avert depression to which Capricorns were considered vulnerable.[20]

In ancient Egypt the colour green (wadj) was associated with death and the power of resurrection as well as new life and fertility. Ancient Egyptians believed that the afterlife contained an eternal paradise, referred to as the "Field of Malachite", which resembled their lives but with no pain or suffering.[21]

See also

References
  1. Mineralienatlas
  2. Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (2003). "Malachite" (PDF). Handbook of Mineralogy. V (Borates, Carbonates, Sulfates). Chantilly, Virginia: Mineralogical Society of America. ISBN 0962209740.
  3. Malachite. Webmineral
  4. Malachite. Mindat
  5. Malachite, Dictionary.com
  6. Harper, Douglas. "malachite". Online Etymology Dictionary.
  7. Johnson, Ben, ed. (2014). "The Great Orme Mines". Retrieved 2017-06-06.
  8. Ruggeri, Amanda (21 April 2016). "The Ancient Copper Mines Dug By Bronze Age Children". BBC. Retrieved 2017-06-06.
  9. Parr, Peter J. (1974). "Review of 'Timma: Valley of the Biblical Copper Mines' by Beno Rothenberg Bulletin of the School of Oriental and African Studies, University of London, Vol. 37, No. 1, pp. 223–224
  10. Куда делись символы России? Argumenty i Fakty (24 May 2006)
  11. Somin, L. M. Тайны седого Урала. Малахит. oldrushistory.ru
  12. Mindat map with over 8500 locations. mindat.org
  13. Klein, Cornelis; Hurlbut, Cornelius S., Jr. (1993). Manual of mineralogy : (after James D. Dana) (21st ed.). New York: Wiley. p. 417. ISBN 047157452X.
  14. "Malachite". American Mineralogical Crystal Structure Database. Department of Geology, University of Arizona. Retrieved 19 December 2020.
  15. "The Red Queen and Her Sisters: Women of Power in Golden Kingdoms". www.metmuseum.org. Retrieved 13 October 2018.
  16. Gettens, R.J. and Fitzhugh, E. W. (1993) "Malachite and Green Verditer", pp. 183–202 in Artists’ Pigments. A Handbook of Their History and Characteristics, Vol. 2: A. Roy (Ed.) Oxford University Press. ISBN 0894682601
  17. The Illustrated Book of Signs and Symbols by Miranda Bruce-Mitford, Dorling Kindersley Limited, London, 1996, p. 41
  18. The Book of Talismans, Amulets and Zodiacal Gems, by William Thomas and Kate Pavitt, [1922], p. 254
  19. The Book of Talismans, Amulets and Zodiacal Gems, by William Thomas and Kate Pavitt, [1922], p. 254
  20. The Book of Talismans, Amulets and Zodiacal Gems, by William Thomas and Kate Pavitt, [1922], p. 254
  21. Hill, J (2010). "Meaning of green in ancient Egypt". Ancient Egypt Online. Retrieved 2016-11-28.

Further reading
  • The dictionary definition of malachite at Wiktionary
  • Media related to Malachite at Wikimedia Commons
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.