Proton affinity (data page)

Proton affinities are quoted in kJ/mol, in increasing order of gas-phase basicity of the base.

BaseProton affinity
(kJ/mol)
Neutral molecules
Helium178
Neon201
Argon371
Dioxygen422
Dihydrogen424
Krypton425
Hydrogen fluoride490
Dinitrogen495
Xenon496
Nitric oxide531
Carbon dioxide548
Methane552
Hydrogen chloride564
Hydrogen bromide569
Nitrous oxide571
Carbon monoxide594
Ethane601
Nitrogen trifluoride602
Hydrogen iodide628
Carbonyl sulfide632
Acetylene641
Arsenic trifluoride649
Silane649
Sulfur dioxide676
Hydrogen peroxide678
Ethylene680
Phosphorus trifluoride697
Water697
Carbon disulfide699
Phosphoryl trifluoride702
2,4-Dicarba-closo-heptaborane(7)703
Hydrogen sulfide712
Hydrogen selenide717
Hydrogen cyanide717
Formaldehyde718
Carbon monosulfide732
Cyanogen chloride735
Arsine750
Benzene759
Methanol761
Methanethiol784
Ethanol788
Acetonitrile788
Phosphine789
Nitrogen trichloride791
Ethanethiol798
Propanol798
Propane-1-thiol802
Hydroxylamine803
Dimethyl ether804
Glyceryl phosphite812
Borazine812
Acetone823
Diethyl ether838
Dimethyl sulfide839
Iron pentacarbonyl845
Ammonia854
Methylphosphine854
Hydrazine856
Diethyl sulfide858
1,6-Dicarba-closo-hexaborane(6)866
Aniline877
P(OCH2)3CCH3877
Ferrocene877
Dimethyl sulfoxide884
Dimethyl formamide884
Trimethyl phosphate887
Trimethylarsine893
Methylamine896
Tri-O-methyl thiophosphate897
Dimethylphosphine905
Trimethyl phosphite923
Dimethylamine923
Pyridine924
Trimethylamine942
Trimethylphosphine950
Triethylphosphine969
Triethylamine972
Lithium hydroxide1008
Sodium hydroxide1038
Potassium hydroxide1100
Caesium hydroxide1125
Anions
Trioxophosphate(1)1301
Iodide1315
Pentacarbonylmanganate(1)1326
Trifluoroacetate1350
Bromide1354
Nitrate1358
Pentacarbonylrhenate(1)1389
Chloride1395
Nitrite1415
Hydroselenide1417
Formate1444
Acetate1458
Phenoxide1470
Cyanide1477
Hydrosulfide1477
Cyclopentadienide1490
Ethanethiolate1495
Nitromethanide1501
Arsinide1502
Methanethiolate1502
Germanide1509
Trichloromethanide1515
Formylmethanide1533
Methylsulfonylmethanide1534
Anilide1536
Acetonide1543
Phosphinide1550
Silanide1554
Fluoride1554
Cyanomethanide1557
Propoxide1568
Acetylide1571
Trifluoromethanide1572
Ethoxide1574
Phenylmethanide1586
Methoxide1587
Hydroxide1635
Amide1672
Hydride1675
Methanide1743

Source: Jolly, William L. (1991). Modern Inorganic Chemistry (2nd Edn.). New York: McGraw-Hill. ISBN 0-07-112651-1.

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