Yttrium(III) sulfate

Yttrium(III) sulfate is an inorganic compound with the formula Y2(SO4)3. The most common form is the anhydrate and octahydrate.

Yttrium(III) sulfate
Names
Other names
Yttrium sesquisulfate
Yttrium sulfate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.480
EC Number
  • 236-844-3
Properties
Y2(SO4)3
Appearance White solid
Soluble
Hazards
GHS pictograms
GHS Signal word Warning
H315, H319, H335
P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Reactions

Yttrium sulfate can form double salts such as MY(SO4)2[1][2][3] and M3Y(SO4)3:[4][5][6]

Y2(SO4)3 + M2SO4 → 2 MY(SO4)2
Y2(SO4)3 + 3 M2SO4 → 2 M3Y(SO4)3 (M=alkali metals)

Synthesis

Yttrium(III) sulfate can be prepared using either corresponding oxide, hydroxide or carbonate.

2 Y(OH)3 + 3 H2SO4 → Y2(SO4)3 + 6 H2O[7]

References
  1. Prokof'ev, M. V.; Pokrovskii, A. N.; Kovba, L. M. Double sulfates of rubidium and rare earth elements. Zhurnal Neorganicheskoi Khimii, 1979. 24(8): 2114-2121. ISSN 0044-457X
  2. Baldanova, D. D.; Evdokimov, A. A.; Petrov, K. I.; Kondratov, O. I.; Fomichev, V. V. X-ray phase analysis and vibrational spectroscopic study of cesium lanthanide sulfate molybdates (in Russian). Deposited Doc.(Report) 1983, 1316-1384. CAN102:71568
  3. Degtiarev, P.A.; Pokrovskii, A.N.; Kovba, L.M.; Korytnaia, F.M. (1977). "Investigation of double sulfates of potassium and rare earth elements with composition KRE(SO4)2". Journal of Solid State Chemistry. 22 (4): 419–422. doi:10.1016/0022-4596(77)90019-6. ISSN 0022-4596.
  4. Prokof'ev, M. V.; Pokrovskii, A. N.; Kovba, L. M. X-ray diffraction study of rubidium lanthanide sulfates (Rb3Ln(SO4)3). Vestnik Moskovskogo Universiteta, Seriya 2: Khimiya, 1979. 20 (6): 571-574. ISSN 0579-9384
  5. Samartsev, B. G.; Pokrovskii, A. N.; Kovba, L. M. X-ray diffraction study of double sulfates, isostructural with cesium neodymium sulfate (Cs3Nd(SO4)3) (in Russian). Vestnik Moskovskogo Universiteta, Seriya 2: Khimiya, 1980. 21 (2): 190-192. ISSN 0579-9384
  6. Kudin, O. V.; Efremov, V. A.; Pokrovskii, A. N.; Degtyarev, P. A.; Trunov, V. K. Synthesis and x-ray diffraction study of double sulfates K3R(SO4)3. Zhurnal Neorganicheskoi Khimii, 1977. 22 (1): 95-97
  7. "Y(OH)3 + H2SO4 = Y2(SO4)3 + H2O | Chemical reaction and equation".
Compounds containing the sulfate group (SO2−
4)
H2SO4 He
Li2SO4 BeSO4 B2S2O9 esters
ROSO3−
(RO)2SO2		 (NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4		 HOSO4 F Ne
Na2SO4
NaHSO4		 MgSO4 Al2(SO4)3
Al2SO4(OAc)4		 Si P SO42−
HSO3HSO4
(HSO4)2		 Cl Ar
K2SO4
KHSO4		 CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4		 CrSO4
Cr2(SO4)3		 MnSO4 FeSO4
Fe2(SO4)3		 CoSO4
Co2(SO4)3		 NiSO4
Ni2(SO4)3		 CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4		 ZnSO4 Ga2(SO4)3 Ge As Se Br Kr
RbHSO4
Rb2SO4		 SrSO4 Y2(SO4)3 Zr(SO4)2 Nb MoSO4
Mo2(SO4)3
Mo(SO4)2
Mo(SO4)2
Mo(SO4)3		 Tc Ru(SO4)2 RhSO4
Rh2(SO4)3		 PdSO4 Ag2SO4
AgSO4		 CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2		 Sb2(SO4)3 Te I Xe
Cs2SO4
CsHSO4		 BaSO4   Hf Ta W Re OsSO4
Os2(SO4)3
Os(SO4)2		 IrSO4
Ir2(SO4)3		 PtSO4
Pt(SO4)2		 AuSO4
Au2(SO4)3		 Hg2SO4
HgSO4		 Tl2SO4
Tl2(SO4)3		 PbSO4
Pb(SO4)2		 Bi2(SO4)3 PoSO4
Po(SO4)2		 At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La2(SO4)3 Ce2(SO4)3
Ce(SO4)2		 Pr2(SO4)3 Nd2(SO4)3 Pm2(SO4)3 Sm2(SO4)3 Eu2(SO4)3 Gd2(SO4)3 Tb2(SO4)3 Dy2(SO4)3 Ho2(SO4)3 Er2(SO4)3 Tm2(SO4)3 Yb2(SO4)3 Lu2(SO4)3
Ac2(SO4)3 Th(SO4)2 Pa U2(SO4)3
U(SO4)2
UO2SO4		 Np(SO4)2 Pu(SO4)2 Am2(SO4)3 Cm2(SO4)3 Bk Cf Es Fm Md No Lr
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