Hazmat suit

DEA agents wearing Level B hazmat suits.

The United States Department of Homeland Security defines a hazmat suit as "an overall garment worn to protect people from hazardous materials or substances, including chemicals, biological agents, or radioactive materials."[1] More generally, hazmat suits may provide protection from:

Chemical agents

through the use of appropriate barrier materials like teflon, heavy PVC or rubber and Tyvek

Nuclear agents

possibly through radiation shielding in the lining, but more importantly by preventing direct contact with or inhalation of radioactive particles or gas

Biological agents

through fully sealed systems—often at overpressure to prevent contamination even if the suit is damaged or using powered air purifying respirators with full hoods and protective suits to prevent exposure (level C protection level)

Fire/high temperatures

usually by a combination of insulating and reflective materials which reduce the effects (see also Fire proximity suit)

The hazmat suit generally includes breathing air supplies to provide clean, uncontaminated air for the wearer. In laboratory use, clean air may be supplied through attached hoses. This air is usually pumped into the suit at positive pressure with respect to the surroundings as an additional protective measure against the introduction of dangerous agents into a potentially ruptured or leaking suit.

Working in a hazmat suit is very strenuous, as the suits tend to be less flexible than conventional work garments. With the exception of laboratory versions, hazmat suits can be hot and poorly ventilated (if at all). Therefore, use is usually limited to short durations of up to 2 hours, depending on the difficulty of the work. Level A (United States) suits, for example, are limited by their air supply to around 15–20 minutes of very strenuous work (such as a firefighting rescue in a building).[2] However, OSHA/EPA protective level A suits/ensembles are not typically used in firefighting rescue, especially during a building/structure fire. National Fire Protection Association (NFPA) compliant "turnout gear", and NIOSH-certified SCBA, or CBRN SCBA, are the primary protection technologies for structure firefighting in the US.

46th Engineer Battalion soldier struggling to put on chemical overshoe boots during search and rescue training at the Muscatatuck Urban Training Center

Hazmat protective clothing is classified as any of Level A, B, C, or D, based upon the degree of protection they provide.[3]

Level A

The highest level of protection against vapors, gases, mists, and particles is Level A, which consists of a fully encapsulating chemical entry suit with a full-facepiece self-contained breathing apparatus (SCBA). A crew member must also wear boots with steel toes and shanks on the outside of the suit and specially selected chemical-resistant gloves for this level of protection. The breathing apparatus is worn inside (encapsulated within) the suit. To qualify as Level A protection, an intrinsically safe two-way radio is also worn inside the suit, often incorporating voice-operated microphones and an earpiece speaker for monitoring the operations channel.

Level B

Level B protection requires a garment (including SCBA) that provides protection against splashes from a hazardous chemical. Since the breathing apparatus is sometimes worn on the outside of the garment, Level B protection is not vapor-protective. Level B suits can also be fully encapsulating, which helps prevent the SCBA from becoming contaminated. It is worn when vapor-protective clothing (Level A) is not required. Wrists, ankles, facepiece and hood, and waist are secured to prevent any entry of splashed liquid. Depending on the chemical being handled, specific types of gloves and boots are donned. These may or may not be attached to the garment. The garment itself may be one piece or a two-piece hooded suit. Level B protection also requires the wearing of chemical-resistant boots with steel toes and shanks on the outside of the garment. As with Level A, chemical-resistant gloves and two-way radio communications are also required.

Level C

Level C protection differs from Level B in the area of equipment needed for respiratory protection. The same type of garment used for Level B protection is worn for Level C. Level C protection allows for the use of respiratory protection equipment other than SCBA. This protection includes any of the various types of air-purifying respirators. Crew members should not use this level of protection unless the specific hazardous material is known and its concentration can be measured. Level C equipment does not offer the protection needed in an oxygen deficient atmosphere.

Level D

Level D protection does not protect the crew member from chemical exposure. Therefore, this level of protection can only be used in situations where a crew member has no possibility of contact with chemicals. A pair of coveralls or other work-type garment along with chemical-resistant footwear with steel toes and shanks are all that is required to qualify as Level D protection. Most firefighter turnout gear is considered to be Level D.

A radiographer wearing a hazmat suit during World War I, France, 1918.

Most suits used in Europe are covered by a set EU Norms, and divided into a total of six types (levels) of protection:

• Type 1: Protects against liquid and gaseous chemicals. Gas tight. (EN 943 part 1). More or less equivalent to US level A.
• Type 2: Protects against liquid and gaseous chemicals. Non gas tight. (EN 943 part 1). More or less equivalent to US level B.¹
• Type 3: Protects against liquid chemicals for a limited period. Liquid jet tight. (EN 14605)
• Type 4: Protects against liquid chemicals for a limited period. Liquid saturation tight. (EN 14605). More or less equivalent to US level C.
• Type 5: Protects against airborne dry particulates for a limited period. (EN ISO 13982-1).
• Type 6: Protects against a light spray of liquid chemicals (EN 13034). More or less equivalent to US level D.

¹: Can be used in places where the chemical in gaseous form isn't harmful to the body exterior.

• 
  Level A/type 1 suit. SCBA is inside suit
• 
  Level B/type 2 suit. SCBA is outside suit
• 
  Level C/type 4 suit
• 
  Type 6 glove made of nitrile rubber

In the GOST system of norms, EN 943 is equivalent to GOST 12.4.284.2-2014.

Different hazmat suits used by Brazilian Military

Following the American standards, there are 4 different types of suits, from A to D. The suits are known to the Brazilian military as Roupa Protetora Permeável de Combate (Protective Permeable Combat Clothing). There are within the Brazilian military several specialized hazmat regiments. The regiments were deployed during the FIFA 2014 World Cup, 2016 Summer Olympics in Rio de Janeiro, and the COVID-19 pandemic.[4]

Such suits (level A in the US) are gas or vapor-tight, providing total encapsulation and the highest level of protection against direct and airborne chemical contact. They are typically worn with a self-contained breathing apparatus (SCBA) enclosed within the suit.

These suits are typically constructed of several layers and, being airtight, include a release valve so the suit does not overinflate from air exhaled by the SCBA. The release valve does retain some air to keep some positive pressure ("overpressure") inside the suit. As noted, such suits are usually limited to just 15–20 minutes of use by their mobile air supply.[2]

With each suit described here, there is a manufactured device designed to protect the respiratory system of the wearer (called a respirator) while the suit/ensemble is used to protect skin exposed to potential hazardous dermal agents. A respirator may be something as simple as a headband strap filtering facepiece respirator (FFR); to a head harness negative pressure full face respirator (air-purifying respirator/APR); to a full face, tight fitting, closed breathing air; or open circuit, self-contained breathing apparatus (CC-SCBA or SCBA).

Tyvek coveralls

Such suits (level B in the US) are not vapor-tight and thus provide a lesser level of protection. They are, however, worn with an SCBA, which may be located inside or outside of the suit, depending on the type of suit (encapsulating or non-encapsulating). They more closely resemble the one-piece Tyvek coveralls often seen used in construction and demolition work. Yet, Level B splash suits may also be fully encapsulating suits which are simply not airtight.

Lesser protection (level C in the US) suits may be coveralls of treated material, or multi-piece combinations, sealed with tape. This kind of protection is still "proof" against many non-invasive substances, such as anthrax.[2]