Triphosphane
Triphosphane (IUPAC systematic name) or triphosphine is an inorganic compound having the chemical formula HP(PH2)2. It can be generated from diphosphine but is highly unstable at room temperature:[3]
- 2 P2H4 → P3H5 + PH3
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Names | |||
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Systematic IUPAC name
Triphosphane[1] | |||
Other names
Triphosphine[2] | |||
Identifiers | |||
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Properties | |||
P 3H 5 | |||
Molar mass | 97.96099 g·mol−1 | ||
Appearance | Colourless gas | ||
Related compounds | |||
Other anions |
triazane | ||
Related Binary phosphanes |
phosphane diphosphane | ||
Related compounds |
triazene | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
verify (what is ?) | |||
Infobox references | |||
Samples to date have been contaminated with P2H4 and P4H6 (both branched and linear isomers).[4]
References
- "triphosphane (CHEBI:35893)". Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. 7 June 2006. Main. Retrieved 27 September 2011.
- "Triphosphine". NIST Chemistry WebBook. USA: National Institute of Standards and Technology. Retrieved 27 September 2011.
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- Marianne Baudler, Klaus Glinka (1993). "Monocyclic and polycyclic phosphines". Chem. Rev. 93: 1623–1667. doi:10.1021/cr00020a010.
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