Isotopes of livermorium

Livermorium (116Lv) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 293Lv in 2000. There are four known radioisotopes from 290Lv to 293Lv, as well as a few suggestive indications of a possible heavier isotope 294Lv. The longest-lived of the four well-characterised isotopes is 293Lv with a half-life of 53 ms.[1]

Main isotopes of livermorium (116Lv)
Iso­tope Decay
abun­dance half-life (t1/2) mode pro­duct
290Lv syn 8 ms α 286Fl
291Lv syn 18 ms α 287Fl
292Lv syn 12 ms α 288Fl
293Lv syn 60 ms α 289Fl
294Lv syn 54 ms? α 290Fl

List of isotopes
Nuclide
 Z N Isotopic mass (Da)
[n 1][n 2]		 Half-life
[n 3]		 Decay
mode
 Daughter
isotope
 Spin and
parity
290Lv[n 4] 116 174 290.19864(71)# 15(+26−6) ms α 286Fl 0+
291Lv 116 175 291.20108(66)# 6.3(+116−25) ms α 287Fl
292Lv 116 176 292.20174(91)# 18.0(+16−6) ms α 288Fl 0+
293Lv 116 177 293.20449(60)# 53(+62−19) ms α 289Fl
294Lv[n 5] 116 178 54 ms#[2] α ? 290Fl 0+
  1. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  2. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  3. # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  4. Not directly synthesized, created as decay product of 294Og
  5. This isotope is unconfirmed

Nucleosynthesis

Target-projectile combinations leading to Z=116 compound nuclei

The below table contains various combinations of targets and projectiles which could be used to form compound nuclei with atomic number 116.

TargetProjectileCNAttempt result
208Pb 82Se290LvFailure to date
238U 54Cr292LvFailure to date
244Pu 50Ti294LvPlanned reaction[3]
250Cm 48Ca298LvReaction yet to be attempted
248Cm 48Ca296LvSuccessful reaction
246Cm 48Ca294LvReaction yet to be attempted
245Cm 48Ca293LvSuccessful reaction
243Cm 48Ca291LvReaction yet to be attempted
248Cm 44Ca292LvReaction yet to be attempted
251Cf 40Ar291LvReaction yet to be attempted

208Pb(82Se,xn)290−xLv

In 1995, the team at GSI attempted the synthesis of 290Lv as a radiative capture (x=0) product. No atoms were detected during a six-week experimental run, reaching a cross section limit of 3 pb.[4]

Hot fusion

This section deals with the synthesis of nuclei of livermorium by so-called "hot" fusion reactions. These are processes which create compound nuclei at high excitation energy (~40–50 MeV, hence "hot"), leading to a reduced probability of survival from fission. The excited nucleus then decays to the ground state via the emission of 3–5 neutrons. Fusion reactions utilizing 48Ca nuclei usually produce compound nuclei with intermediate excitation energies (~30–35 MeV) and are sometimes referred to as "warm" fusion reactions. This leads, in part, to relatively high yields from these reactions.

238U(54Cr,xn)292−xLv

There are sketchy indications that this reaction was attempted by the team at GSI in 2006. There are no published results on the outcome, presumably indicating that no atoms were detected. This is expected from a study of the systematics of cross sections for 238U targets.[5]

248Cm(48Ca,xn)296−xLv (x=2,3,4,5?)

The first attempt to synthesise livermorium was performed in 1977 by Ken Hulet and his team at the Lawrence Livermore National Laboratory (LLNL). They were unable to detect any atoms of livermorium.[6] Yuri Oganessian and his team at the Flerov Laboratory of Nuclear Reactions (FLNR) subsequently attempted the reaction in 1978 and met failure. In 1985, a joint experiment between Berkeley and Peter Armbruster's team at GSI, the result was again negative with a calculated cross-section limit of 10–100 pb.[7]

In 2000, Russian scientists at Dubna finally succeeded in detecting a single atom of livermorium, assigned to the isotope 292Lv.[8] In 2001, they repeated the reaction and formed a further 2 atoms in a confirmation of their discovery experiment. A third atom was tentatively assigned to 293Lv on the basis of a missed parental alpha decay.[9] In April 2004, the team ran the experiment again at higher energy and were able to detect a new decay chain, assigned to 292Lv. On this basis, the original data were reassigned to 293Lv. The tentative chain is therefore possibly associated with a rare decay branch of this isotope or an isomer, 293mLv; given the possible reassignment of its daughter to 290Fl instead of 289Fl, it could also conceivably be 294Lv, although all these assignments are tentative and need confirmation in future experiments aimed at the 2n channel.[10] In this reaction, 2 further atoms of 293Lv were detected.[11]

In 2007, in a GSI-SHIP experiment, besides four 292Lv chains and one 293Lv chain, another chain was observed, initially not assigned but later shown to be 291Lv. However, it is unclear whether it comes from the 248Cm(48Ca,5n) reaction or from a reaction with a lighter curium isotope (present in the target as an admixture), such as 246Cm(48Ca,3n).[12][13]

In an experiment run at the GSI during June–July 2010, scientists detected six atoms of livermorium; two atoms of 293Lv and four atoms of 292Lv. They were able to confirm both the decay data and cross sections for the fusion reaction.[14]

A 2016 experiment at RIKEN aimed at studying the 48Ca+248Cm reaction seemingly detected one atom that may be assigned to 294Lv alpha decaying to 290Fl and 286Cn, which underwent spontaneous fission; however, the first alpha from the livermorium nuclide produced was missed.[2]

245Cm(48Ca,xn)293−xLv (x=2,3)

In order to assist in the assignment of isotope mass numbers for livermorium, in March–May 2003 the Dubna team bombarded a 245Cm target with 48Ca ions. They were able to observe two new isotopes, assigned to 291Lv and 290Lv.[15] This experiment was successfully repeated in February–March 2005 where 10 atoms were created with identical decay data to those reported in the 2003 experiment.[16]

As a decay product

Livermorium has also been observed in the decay of oganesson. In October 2006 it was announced that 3 atoms of oganesson had been detected by the bombardment of californium-249 with calcium-48 ions, which then rapidly decayed into livermorium.[16]

The observation of the daughter 290Lv allowed the assignment of the parent to 294Og and proved the synthesis of oganesson.

Fission of compound nuclei with Z=116

Several experiments have been performed between 2000 and 2006 at the Flerov Laboratory of Nuclear Reactions in Dubna studying the fission characteristics of the compound nuclei 296,294,290Lv. Four nuclear reactions have been used, namely 248Cm+48Ca, 246Cm+48Ca, 244Pu+50Ti, and 232Th+58Fe. The results have revealed how nuclei such as this fission predominantly by expelling closed shell nuclei such as 132Sn (Z=50, N=82). It was also found that the yield for the fusion-fission pathway was similar between 48Ca and 58Fe projectiles, indicating a possible future use of 58Fe projectiles in superheavy element formation. In addition, in comparative experiments synthesizing 294Lv using 48Ca and 50Ti projectiles, the yield from fusion-fission was ~3x less for 50Ti, also suggesting a future use in SHE production.[17]

289Lv

In 1999, researchers at Lawrence Berkeley National Laboratory announced the synthesis of 293Og (see oganesson), in a paper published in Physical Review Letters.[18] The claimed isotope 289Lv decayed by 11.63 MeV alpha emission with a half-life of 0.64 ms. The following year, they published a retraction after other researchers were unable to duplicate the results.[19] In June 2002, the director of the lab announced that the original claim of the discovery of these two elements had been based on data fabricated by the principal author Victor Ninov. As such, this isotope of livermorium is currently unknown.

Chronology of isotope discovery
IsotopeYear discoveredDiscovery reaction
290Lv2002249Cf(48Ca,3n)[20]
291Lv2003245Cm(48Ca,2n)[15]
292Lv2004248Cm(48Ca,4n)[11]
293Lv2000248Cm(48Ca,3n)[8]
294Lv ??2001248Cm(48Ca,2n) ?[10]

Yields of isotopes

Hot fusion

The table below provides cross-sections and excitation energies for hot fusion reactions producing livermorium isotopes directly. Data in bold represent maxima derived from excitation function measurements. + represents an observed exit channel.

ProjectileTargetCN2n3n4n5n
48Ca248Cm296Lv1.1 pb, 38.9 MeV[11]3.3 pb, 38.9 MeV[11]
48Ca245Cm293Lv0.9 pb, 33.0 MeV[15]3.7 pb, 37.9 MeV[15]

Theoretical calculations

Decay characteristics

Theoretical calculation in a quantum tunneling model supports the experimental data relating to the synthesis of 293Lv and 292Lv.[21][22]

Evaporation residue cross sections

The below table contains various targets-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

DNS = Di-nuclear system; σ = cross section

TargetProjectileCNChannel (product)σmaxModelRef
208Pb 82Se290Lv1n (289Lv)0.1 pbDNS[23]
208Pb 79Se287Lv1n (286Lv)0.5 pbDNS[23]
238U 54Cr292Lv2n (290Lv)0.1 pbDNS[24]
250Cm 48Ca298Lv4n (294Lv)5 pbDNS[24]
248Cm 48Ca296Lv4n (292Lv)2 pbDNS[24]
247Cm 48Ca295Lv3n (292Lv)3 pbDNS[24]
245Cm 48Ca293Lv3n (290Lv)1.5 pbDNS[24]
243Cm 48Ca291Lv3n (288Lv)1.53 pbDNS[25]
248Cm 44Ca292Lv4n (288Lv)0.43 pbDNS[25]

References
  1. "Livermorium - Element Information (Uses and properties)". rsc.org. Retrieved October 27, 2020.
  2. Kaji, Daiya; Morita, Kosuke; Morimoto, Kouji; Haba, Hiromitsu; Asai, Masato; Fujita, Kunihiro; Gan, Zaiguo; Geissel, Hans; Hasebe, Hiroo; Hofmann, Sigurd; Huang, MingHui; Komori, Yukiko; Ma, Long; Maurer, Joachim; Murakami, Masashi; Takeyama, Mirei; Tokanai, Fuyuki; Tanaka, Taiki; Wakabayashi, Yasuo; Yamaguchi, Takayuki; Yamaki, Sayaka; Yoshida, Atsushi (2017). "Study of the Reaction 48Ca + 248Cm → 296Lv* at RIKEN-GARIS". Journal of the Physical Society of Japan. 86 (3): 034201–1–7. Bibcode:2017JPSJ...86c4201K. doi:10.7566/JPSJ.86.034201.
  3. http://flerovlab.jinr.ru/flnr/programme_synth_2020.html
  4. Hoffman, Darleane C.; Ghiorso, Albert; Seaborg, Glenn T. (2000). The Transuranium People: The Inside Story. World Scientific. p. 367. ISBN 978-1-78-326244-1.
  5. "List of experiments 2000–2006" Archived 2007-07-23 at the Wayback Machine
  6. Hulet, E. K.; Lougheed, R.; Wild, J.; Landrum, J.; Stevenson, P.; Ghiorso, A.; Nitschke, J.; Otto, R.; et al. (1977). "Search for Superheavy Elements in the Bombardment of 248Cm with48Ca". Physical Review Letters. 39 (7): 385–389. Bibcode:1977PhRvL..39..385H. doi:10.1103/PhysRevLett.39.385.
  7. Armbruster, P.; Agarwal, YK; Brüchle, W; Brügger, M; Dufour, JP; Gaggeler, H; Hessberger, FP; Hofmann, S; et al. (1985). "Attempts to Produce Superheavy Elements by Fusion of 48Ca with 248Cm in the Bombarding Energy Range of 4.5–5.2 MeV/u". Physical Review Letters. 54 (5): 406–409. Bibcode:1985PhRvL..54..406A. doi:10.1103/PhysRevLett.54.406. PMID 10031507.
  8. Oganessian, Yu. Ts.; Utyonkov, V.; Lobanov, Yu.; Abdullin, F.; Polyakov, A.; Shirokovsky, I.; Tsyganov, Yu.; Gulbekian, G.; Bogomolov, S.; Gikal, B.; Mezentsev, A.; Iliev, S.; Subbotin, V.; Sukhov, A.; Ivanov, O.; Buklanov, G.; Subotic, K.; Itkis, M.; Moody, K.; Wild, J.; Stoyer, N.; Stoyer, M.; Lougheed, R.; Laue, C.; Karelin, Ye.; Tatarinov, A. (2000). "Observation of the decay of 292116". Physical Review C. 63 (1): 011301. Bibcode:2001PhRvC..63a1301O. doi:10.1103/PhysRevC.63.011301.
  9. "Confirmed results of the 248Cm(48Ca,4n)292116 experiment" Archived 2016-01-30 at the Wayback Machine, Patin et al., LLNL report (2003). Retrieved 2008-03-03
  10. Hofmann, S.; Heinz, S.; Mann, R.; Maurer, J.; Münzenberg, G.; Antalic, S.; Barth, W.; Burkhard, H. G.; Dahl, L.; Eberhardt, K.; Grzywacz, R.; Hamilton, J. H.; Henderson, R. A.; Kenneally, J. M.; Kindler, B.; Kojouharov, I.; Lang, R.; Lommel, B.; Miernik, K.; Miller, D.; Moody, K. J.; Morita, K.; Nishio, K.; Popeko, A. G.; Roberto, J. B.; Runke, J.; Rykaczewski, K. P.; Saro, S.; Scheidenberger, C.; Schött, H. J.; Shaughnessy, D. A.; Stoyer, M. A.; Thörle-Popiesch, P.; Tinschert, K.; Trautmann, N.; Uusitalo, J.; Yeremin, A. V. (2016). "Review of even element super-heavy nuclei and search for element 120". The European Physical Journal A. 2016 (52): 180. Bibcode:2016EPJA...52..180H. doi:10.1140/epja/i2016-16180-4. S2CID 124362890.
  11. Oganessian, Yu. Ts.; Utyonkov, V.; Lobanov, Yu.; Abdullin, F.; Polyakov, A.; Shirokovsky, I.; Tsyganov, Yu.; Gulbekian, G.; Bogomolov, S.; Gikal, B.; Mezentsev, A.; Iliev, S.; Subbotin, V.; Sukhov, A.; Voinov, A.; Buklanov, G.; Subotic, K.; Zagrebaev, V.; Itkis, M.; Patin, J.; Moody, K.; Wild, J.; Stoyer, M.; Stoyer, N.; Shaughnessy, D.; Kenneally, J.; Wilk, P.; Lougheed, R.; Il’kaev, R.; Vesnovskii, S. (2004). "Measurements of cross sections and decay properties of the isotopes of elements 112, 114, and 116 produced in the fusion reactions 233,238U, 242Pu, and 248Cm+48Ca" (PDF). Physical Review C. 70 (6): 064609. Bibcode:2004PhRvC..70f4609O. doi:10.1103/PhysRevC.70.064609.
  12. Hofmann, S.; Heinz, S.; Mann, R.; Maurer, J.; Khuyagbaatar, J.; Ackermann, D.; Antalic, S.; Barth, W.; Block, M.; Burkhard, H. G.; Comas, V. F.; Dahl, L.; Eberhardt, K.; Gostic, J.; Henderson, R. A.; Heredia, J. A.; Heßberger, F. P.; Kenneally, J. M.; Kindler, B.; Kojouharov, I.; Kratz, J. V.; Lang, R.; Leino, M.; Lommel, B.; Moody, K. J.; Münzenberg, G.; Nelson, S. L.; Nishio, K.; Popeko, A. G.; et al. (2012). "The reaction 48Ca + 248Cm → 296116* studied at the GSI-SHIP". The European Physical Journal A. 48 (5): 62. Bibcode:2012EPJA...48...62H. doi:10.1140/epja/i2012-12062-1. S2CID 121930293.
  13. Oganessian, Yu. Ts.; Utyonkov, V. (2015). "Super-heavy element research". Reports on Progress in Physics. 78 (3): 036301. Bibcode:2015RPPh...78c6301O. doi:10.1088/0034-4885/78/3/036301. PMID 25746203.
  14. Hoffman, S.; et al. (2012). "The reaction 48Ca + 248Cm → 296116* studied at the GSI-SHIP". European Physical Journal A. 48 (62). Bibcode:2012EPJA...48...62H. doi:10.1140/epja/i2012-12062-1. S2CID 121930293.
  15. Oganessian, Yu. Ts.; Utyonkov, V.; Lobanov, Yu.; Abdullin, F.; Polyakov, A.; Shirokovsky, I.; Tsyganov, Yu.; Gulbekian, G.; et al. (2004). "Measurements of cross sections for the fusion-evaporation reactions244Pu(48Ca,xn)292−x114 and 245Cm(48Ca,xn)293−x116". Physical Review C. 69 (5): 054607. Bibcode:2004PhRvC..69e4607O. doi:10.1103/PhysRevC.69.054607.
  16. "Synthesis of the isotopes of elements 118 and 116 in the 249Cf and 245Cm+48Ca fusion reactions". Cite journal requires |journal= (help)
  17. see Flerov lab annual reports 2000–2006
  18. Ninov, V.; et al. (1999). "Observation of Superheavy Nuclei Produced in the Reaction of86Kr with 208Pb". Physical Review Letters. 83 (6): 1104–1107. Bibcode:1999PhRvL..83.1104N. doi:10.1103/PhysRevLett.83.1104.
  19. Ninov, V.; Gregorich, K.; Loveland, W.; Ghiorso, A.; Hoffman, D.; Lee, D.; Nitsche, H.; Swiatecki, W.; Kirbach, U.; Laue, C.; Adams, J.; Patin, J.; Shaughnessy, D.; Strellis, D.; Wilk, P. (2002). "Editorial Note: Observation of Superheavy Nuclei Produced in the Reaction of ^{86}Kr with ^{208}Pb [Phys. Rev. Lett. 83, 1104 (1999)]". Physical Review Letters. 89 (3): 039901. Bibcode:2002PhRvL..89c9901N. doi:10.1103/PhysRevLett.89.039901.
  20. see oganesson
  21. P. Roy Chowdhury; C. Samanta; D. N. Basu (2006). "α decay half-lives of new superheavy elements". Physical Review C. 73 (1): 014612. arXiv:nucl-th/0507054. Bibcode:2006PhRvC..73a4612C. doi:10.1103/PhysRevC.73.014612. S2CID 118739116.
  22. C. Samanta; P. Roy Chowdhury; D. N. Basu (2007). "Predictions of alpha decay half lives of heavy and superheavy elements". Nuclear Physics A. 789 (1–4): 142–154. arXiv:nucl-th/0703086. Bibcode:2007NuPhA.789..142S. doi:10.1016/j.nuclphysa.2007.04.001. S2CID 7496348.
  23. Feng, Zhao-Qing; Jin, Gen-Ming; Li, Jun-Qing; Scheid, Werner (2007). "Formation of superheavy nuclei in cold fusion reactions". Physical Review C. 76 (4): 044606. arXiv:0707.2588. Bibcode:2007PhRvC..76d4606F. doi:10.1103/PhysRevC.76.044606. S2CID 711489.
  24. Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A. 816 (1–4): 33–51. arXiv:0803.1117. Bibcode:2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. S2CID 18647291.
  25. Zhu, L.; Su, J.; Zhang, F. (2016). "Influence of the neutron numbers of projectile and target on the evaporation residue cross sections in hot fusion reactions". Physical Review C. 93 (6). doi:10.1103/PhysRevC.93.064610.
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