Potassium heptafluorotantalate

Potassium heptafluorotantalate is an inorganic compound with the formula K2[TaF7]. It is the potassium salt of the heptafluorotantalate anion [TaF7]2−. This white, water-soluble solid is an intermediate in the purification of tantalum from its ores and is the precursor to the metal.[2]

Potassium heptafluorotantalate
Names
IUPAC name
Dipotassium heptafluorotantalate
Systematic IUPAC name
Dipotassium heptafluorotantalum(2-)
Other names
Potassium heptafluorotantalate(V)
Potassium fluorotantalate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.037.245
EC Number
  • 240-986-1
Properties
K2[TaF7]
Molar mass 392.13 g/mol
Appearance white solid
Density 4.56 g/mL at 25 °C
Melting point 630 to 820 °C (1,166 to 1,508 °F; 903 to 1,093 K)
0.5 g/100 mL (15 °C)[1]
Hazards
GHS pictograms
GHS Signal word Danger
H301, H315, H319, H331, H335
P261, P264, P270, P271, P280, P301+310, P302+352, P304+340, P305+351+338, P311, P312, P321, P330, P332+313, P337+313, P362, P403+233, P405, P501
Lethal dose or concentration (LD, LC):
110 mg/kg (Oral: rat)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Preparation

Industrial
Further information: Tantalum § Production and fabrication

Potassium heptafluorotantalate is an intermediate in the industrial production of metallic tantalum. Its production involves leaching tantalum ores, such as columbite and tantalite, with hydrofluoric acid and sulfuric acid to produce the water-soluble hydrogen pentafluorotantalate.[2]

Ta2O5 + 14 HF → 2 H2[TaF7] + 5 H2O

This solution is subjected to a number of liquid-liquid extraction steps to remove metallic impurities (most importantly niobium) before being treated with potassium fluoride to produce K2[TaF7]

H2[TaF7] + 2 KF → K2[TaF7] + 2 HF

Lab-scale

Hydrofluoric acid is both corrosive and toxic, making it unappealing to work with; as such a number of alternative processes have been developed for small-scale syntheses. Potassium heptafluorotantalate can be produced by both anhydrous and wet methods. The anhydrous method involves the reaction of tantalum oxide with potassium bifluoride or ammonium bifluoride according to the following equation:[1][3]

Ta2O5 + 4 KHF2 + 6 HF → 2 K2[TaF7] + 5 H2O

The method was originally reported by Berzelius.[4]

K2[TaF7] can also be precipitated from solutions in hydrofluoric acid provided that the concentration of HF is below about 42%. Solutions having higher concentrations of HF yield potassium hexafluorotantalate [KTaF6]. The K-salt can be also precipitated from a solution in hydrofluoric acid of tantalum pentachloride:

5 HF + 2 KF + TaCl5 → K2[TaF7] + 5 HCl

Structure

Potassium heptafluorotantalate exists in at least two polymorphs. α-K2[TaF7] is the most common form and crystallises in the monoclinic P21/c space group.[5] The structure is composed of [TaF7]2− units interconnected by potassium ions. [TaF7]2− polyhedra may be described as monocapped trigonal prisms with the capping atom located on one of the rectangular faces. Potassium atoms are 9-coordinated and may be viewed as distorted monocapped square prisms.

At temperatures above 230 °C this converts to β-K2[TaF7], which is orthorhombic (space group: Pnma). This structure also consists of potassium ions and the complex anion [TaF7]2−. The structure of the 7-coordinate [TaF7]2− units is essentially unchanged. However the potassium atoms now exist in 2 environments where they coordinate to either 11 or 8 fluorine atoms.[6][7]

Reactions

K2[TaF7] is primarily used to produce metallic tantalum by reduction with sodium. This takes place at approximately 800 °C in molten salt and proceeds via a number of potential pathways.[8]

K2[TaF7] + 5 Na → Ta + 5 NaF + 2 KF

K2[TaF7] is susceptible to hydrolysis. For example, a boiling aqueous solution of K2[TaF7] yields potassium oxyfluorotantalate (K2Ta2O3F6), known as “Marignac’s salt”. In order to prevent hydrolysis and co-precipitation of potassium oxyfluorotantalate, a small excess of HF is added to the solution.

References
  1. Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 256.
  2. Anthony Agulyanski (2004). "Fluorine chemistry in the processing of tantalum and niobium". In Anatoly Agulyanski (ed.). Chemistry of Tantalum and Niobium Fluoride Compounds (1st ed.). Burlington: Elsevier. ISBN 9780080529028.
  3. Agulyansky, A. "Potassium fluorotantalate in solid, dissolved and molten conditions" J. Fluorine Chemistry 2003, 155-161. doi:10.1016/S0022-1139(03)00190-8
  4. J. J. Berzelius Pogg. Ann. 4, 6 (1825#.
  5. Torardi, C.C.; Brixner, L.H.; Blasse, G. (1987). "Structure and luminescence of K2TaF7 and K2NbF7". Journal of Solid State Chemistry. 67 (1): 21–25. doi:10.1016/0022-4596#87)90333-1.
  6. Langer, V. Smrčok, L. Boča, M. "Dipotassium heptafluorotantalate#V#, β-K2TaF7, at 509K" Acta Crystallographica Section E 2006, E62, i91-i93. doi:10.1107/S1600536806009147
  7. Smrčok, Ľubomír; Brunelli, Michela; Boča, Miroslav; Kucharík, Marian (8 April 2008). "Structure of K2TaF7 at 993 K: the combined use of synchrotron powder data and solid-state DFT calculations". Journal of Applied Crystallography. 41 (3): 634–636. doi:10.1107/S0021889808005876.
  8. Okabe, Toru H.; Sadoway, Donald R. (1998). "Metallothermic reduction as an electronically mediated reaction". Journal of Materials Research. 13 (12): 3372–3377. Bibcode:1998JMatR..13.3372O. doi:10.1557/JMR.1998.0459.
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