Chemical hazard

A chemical hazard is a type of occupational hazard caused by exposure to chemicals in the workplace. Exposure to chemicals in the workplace can cause acute or long-term detrimental health effects. There are many types of hazardous chemicals, including neurotoxins, immune agents, dermatologic agents, carcinogens, reproductive toxins, systemic toxins, asthmagens, pneumoconiotic agents, and sensitizers.[1] These hazards can cause physical and/or health risks. Depending on chemical, the hazards involved may be varied, thus it is important to know and apply the PPE especially during the lab.[2]

A chemical burn

Long-term exposure to chemicals such as silica dust, engine exhausts, tobacco smoke, and lead (among others) have been shown to increase risk of heart disease, stroke, and high blood pressure.[3]

The Two Types of Chemical Hazards

Physical Hazard Example
Flammable and Combustible Liquids Diesel
Compressed Gases Propane
Explosives TNT
Organic Peroxides Methyl ethyl ketone peroxide; a chemical used in the manufacturing of polyester
Reactives Benzoyl peroxide; used as a bleaching agent
Oxidizers Potassium
Pyrophorics White phosphorus
Health Hazards Example
Carcinogens Benzene; used to make lubricants
Reproductive Toxins Lead
Irritants Hydrochloric acid; used in food manufacturing and ore processing
Corrosives Sulfuric acid; used to manufacture chemicals
Sensitizers Latex; used to manufacture gloves
Hepatotoxins Trichlorethylene; chemical found in veterinary anti-parasite medication
Nephrotoxins Naproxen (also known as Ibuprofen)

The Four Major Routes of Exposure

  • Inhalation

The most common exposure route to chemicals in the work environment is through inhalation. Gas, vapor, mist, dust, fumes, and smoke are all chemicals that can be inhaled. Chemicals are inhaled when a worker breathes in contaminated air through their mouth and/or nose and then subsequently into their lungs. Those with occupations involving physical work will inhale higher levels of chemicals. This is because workers who do physical work will exchange over 10,000 liters of air over a 8-hour day, while workers who do not do physical work will exchange only 2,800 liters.[4] If the air is contaminated in the workplace, more air exchange will lead to the inhalation of higher amounts of chemicals.

  • Ingestion

The ingestion of chemicals occurs when chemicals enter into the worker’s mouth and are swallowed. Ingesting chemicals commonly occurs when food and/or drink is contaminated by unwashed hands, personal protective equipment, and/or clothing.

  • Contact with Skin and or Eyes

Chemical exposure to the skin is a common workplace injury. The exposure of chemicals to the skin most often results in local irritation to the exposed area. In some exposures, the chemical will be absorbed through the skin and will result in poisoning. The eyes have a strong sensitivity to chemicals, and are consequently an area of high concern for chemical exposure. Chemical exposure to the eyes results in irritation and, in many instances, burns and vision loss.

  • Injection

Injection is the most uncommon method of chemical exposure in the workplace. Chemicals can be injected into the skin when a worker is punctured by a sharp object, such as a needle. Chemical exposure through injection results in the chemical entering directly into the bloodstream.

Symbols

Hazard pictographs are a type of labeling system that alerts people at a glance that there are hazardous chemicals present. The symbols help identify whether the chemicals that are going to be in use may potentially cause physical harm, or harm to the environment. The symbols are distinctive, as they are shaped like diamonds with red borders. These signs can be divided into:

  • Explosive (exploding bomb)
  • Flammable (flame)
  • Oxidizing (flame above a circle)
  • Corrosive (corrosion of table and hand)
  • Acute toxicity (skull and crossbones)
  • Hazardous to environment (dead tree and fish)
  • Health hazard/hazardous to the ozone layer (exclamation mark)
  • Serious health hazard (cross on a human silhouette)
  • Gas under pressure (gas cylinder)[5]

These pictographs are also subdivided into class and categories for each classification. The assignments for each chemical depends on their type and their severity.

Controlling Exposure

  • Elimination and Substitution

Chemical exposure is estimated to have caused approximately 190,000 illnesses and 50,000 deaths of workers annually.[6] There exists an unknown link between chemical exposure and subsequent illness and/or death. Therefore, the majority of these illnesses and deaths are thought to be caused by a lack of knowledge and/or awareness concerning the dangers of chemicals. The best method of controlling chemical exposure within the workplace is through the elimination or the substitution of all chemicals that are thought or known to cause illness and/or death.

  • Engineering Controls

Although the elimination and the substitution of the harmful chemicals is the best known method for controlling chemical exposure, there are other methods that can be implemented to diminish exposure. The implementation of engineering controls is an example of another method for controlling chemical exposures. When engineer controls are implemented, there is a physical change made to the work environment that will eliminate or reduce the risk to chemical exposure. An example of engineer controls is the enclosure or isolation of the process that creates the chemical hazard.

  • Administrative and Work Practices Controls

If the process that creates the chemical hazard cannot be enclosed or isolated, the next best method is the implementation of administrative and work practices controls. This is the establishment of administrate and work practices that will reduce the amount of time and how often the workers will be exposed to the chemical hazard. An example of administrative and work practices controls is the establishment of work schedules in which workers have rotating job assignments. This will ensure that all workers have limited exposure to chemical hazards.

  • Personal Protective Equipment (PPE)

Employers should provide personal protective equipment (PPE) to protect their workers from chemicals used within the workplace. The use of PPE prevents workers from being exposed to chemicals through the routes of exposure—inhalation, absorption through skin and/or eyes, ingestion, and injection. One example of how PPE usage can prevent chemical exposure concerns respirators. If workers wear respirators, they will prevent the exposure of chemicals through inhalation.

First aid

In case of emergency, it is recommended to understand first aid procedures in order to minimize any damage. Different types of chemicals can cause a variety of damage. Most sources agree that it is best to rinse any contacted skin or eye with water immediately. Currently, there is insufficient evidence of how long the rinsing should be done, as the degree of impacts will vary for substances such as corrosive chemicals. However, the recommended flush time is as follows:

  • 5 minutes - non- to mild irritants
  • 15 minutes - moderate to severe irritants and chemicals that cause acute toxicity
  • 30 minutes - most corrosives
  • 60 minutes - strong alkalis such as sodium, potassium or calcium hydroxide

Transporting the affected person to a health care facility may be important, depending on condition. In the case that the victim needs to be transported before the recommended flush time, then flushing should be done during the transportation process. Some chemical manufacturers may state the specific type of cleansing agent that is recommended.[7]

Long-term risks

Cardiovascular disease

A 2017 SBU report found evidence that workplace exposure to silica dust, engine exhaust or welding fumes is associated with heart disease.[3] Associations also exist for exposure to arsenic, benzopyrenes, lead, dynamite, carbon disulphide, carbon monoxide, metalworking fluids and occupational exposure to tobacco smoke.[3] Working with the electrolytic production of aluminium, or the production of paper when the sulphate pulping process is used, is associated with heart disease.[3] An association was also found between heart disease and exposure to compounds which are no longer permitted in certain work environments, such as phenoxy acids containing TCDD (dioxin) or asbestos.[3]

Workplace exposure to silica dust or asbestos is also associated with pulmonary heart disease. There is evidence that workplace exposure to lead, carbon disulphide, or phenoxyacids containing TCDD, as well as working in an environment where aluminium is being electrolytically produced, are associated with stroke.[3]

See also

References

  1. "CDC - Chemical Safety - NIOSH Workplace Safety and Health Topic". www.cdc.gov. Retrieved 2015-09-03.
  2. "Chapter 8 - Chemical Hazards". sp.ehs.cornell.edu. Retrieved 2016-02-02.
  3. "Occupational health and safety – chemical exposure". www.sbu.se. Swedish Agency for Health Technology Assessment and Assessment of Social Services (SBU). Archived from the original on 2017-06-06. Retrieved 2017-06-01.
  4. Government of Canada, Canadian Centre for Occupational Health and Safety (2020-11-12). "Canadian Centre for Occupational Health and Safety". www.ccohs.ca. Retrieved 2020-12-01.
  5. "Hazard symbols and hazard pictograms - Chemical classification". hse.gov.uk. Health and Safety Executive. Retrieved 2016-02-11.
  6. "Why Transition? | Transitioning to Safer Chemicals | Occupational Safety and Health Administration". www.osha.gov. Retrieved 2020-12-01.
  7. Safety, Government of Canada, Canadian Centre for Occupational Health and. "First Aid for Chemical Exposures : OSH Answers". www.ccohs.ca. Retrieved 2016-03-17.
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